(chloromethyl)ethyldiphenylgermane

Base Information

Chemical Name:(chloromethyl)ethyldiphenylgermane
CAS No.:132872-04-9
Molecular Formula:C₁₅H₁₇ClGe
Molecular Weight:305.343
Hs Code.:

Synonyms:(chloromethyl)ethyldiphenylgermane

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Chemical Property of (chloromethyl)ethyldiphenylgermane

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Technology Process of (chloromethyl)ethyldiphenylgermane

There total 1 articles about (chloromethyl)ethyldiphenylgermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 925-90-6
ethylmagnesium bromide

: 21572-18-9
trichloro(chloromethyl)germane

: 100-58-3
phenylmagnesium bromide

: 132872-04-9
(chloromethyl)ethyldiphenylgermane

Guidance literature:: In diethyl ether; (dry N2); addn. of PhMgBr prepd. from Mg/PhBr in dry Et2O to soln. of GeCH2Cl4 in dry Et2O during 1 h at 0°C, stirring at 0°C (4 h), addn. of EtMgBr prepd. from Mg/EtBr in dry Et2O during 1 h at 0°C, stirring at room temp. overnight; sepn. of org. layer after hydrolyzation, extn. of aq. layer (Et2O, three times), drying combined the org. layer and exts. (Na2SO4), evapn., distn. of the residue;
DOI:10.1246/bcsj.67.160

Reference yield: 94.0%

: 132872-04-9
(chloromethyl)ethyldiphenylgermane

: 100-46-9
benzylamine

: 132872-05-0
N-(ethyldiphenylgermylmethyl)benzylamine

Guidance literature:: In neat (no solvent); (dry N2); stirring mixt. of Ge-compd. and large excess of PhCH2NH2 at 80°C (18 h); addn. of aq. 2 M NaOH, sepn. of the org. layer, extn. of the aq. layer (Et2O, three times), drying the combined org. layer and exts. (Na2SO4), evapn., chromy. (silica gel, hexane/ethyl acetate 5:1); mass spectroscopic examn.;
DOI:10.1246/bcsj.67.160

Reference yield: 64.0%

: 132872-04-9
(chloromethyl)ethyldiphenylgermane

: 154849-32-8
(ethyldiphenylgermyl)methylamine

Guidance literature:: With ammonia; In neat (no solvent); (dry N2); stirring mixt. of Ge-compd. and large excess of NH3 at 80°C (18 h); addn. of aq. 2 M NaOH, sepn. of the org. layer, extn. of the aq. layer (Et2O, three times), drying the combined org. layer and exts. (Na2SO4), evapn., chromy. (silica gel, hexane/ethyl acetate 5:1); mass spectroscopic examn.;
DOI:10.1246/bcsj.67.160