tert-butyl-{4-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-[2-(4-methoxy-benzyloxy)-ethyl]-but-2-enyloxy}-dimethyl-silane

Base Information

Chemical Name:tert-butyl-{4-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-[2-(4-methoxy-benzyloxy)-ethyl]-but-2-enyloxy}-dimethyl-silane
CAS No.:934473-37-7
Molecular Formula:C₃₆H₅₆O₅Si
Molecular Weight:596.923
Hs Code.:

<i>tert</i>-butyl-{4-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-[2-(4-methoxy-benzyloxy)-ethyl]-but-2-enyloxy}-dimethyl-silane

Synonyms:tert-butyl-{4-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-[2-(4-methoxy-benzyloxy)-ethyl]-but-2-enyloxy}-dimethyl-silane

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Chemical Property of tert-butyl-{4-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-[2-(4-methoxy-benzyloxy)-ethyl]-but-2-enyloxy}-dimethyl-silane

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Technology Process of tert-butyl-{4-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-[2-(4-methoxy-benzyloxy)-ethyl]-but-2-enyloxy}-dimethyl-silane

There total 20 articles about tert-butyl-{4-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-[2-(4-methoxy-benzyloxy)-ethyl]-but-2-enyloxy}-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 934473-30-0
6-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-(4-methoxy-benzyloxy)-hex-4-en-3-ol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 934473-37-7
tert-butyl-{4-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-[2-(4-methoxy-benzyloxy)-ethyl]-but-2-enyloxy}-dimethyl-silane

Guidance literature:: With 1H-imidazole; In dichloromethane; at 20 ℃;
DOI:10.1016/j.tetlet.2007.01.056

Reference yield:

: 86088-39-3
2-(5-phenylbutyl)oxirane

: 934473-37-7
tert-butyl-{4-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-[2-(4-methoxy-benzyloxy)-ethyl]-but-2-enyloxy}-dimethyl-silane

Guidance literature:: Multi-step reaction with 10 steps

1: 42 percent / (R,R)-(salen)Co(III)(OAc) / H₂O

2: 71 percent / CuI / tetrahydrofuran / 20 °C

3: 92 percent / imidazole / CH₂Cl₂ / 20 °C

4: 96 percent / m-CPBA / CH₂Cl₂ / 20 °C

5: 41 percent / (S,S)-(salen)Co(III)(OAc) / H₂O

6: 72 percent / n-BuLi; BF₃*OEt₂ / tetrahydrofuran / -78 °C

7: 87 percent / TBAF / tetrahydrofuran / 20 °C

8: 95 percent / PTSA / CH₂Cl₂ / 20 °C

9: 85 percent / LAH / tetrahydrofuran / 20 °C

10: 98 percent / imidazole / CH₂Cl₂ / 20 °C

With 1H-imidazole; copper(l) iodide; lithium aluminium tetrahydride; (S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate; n-butyllithium; (R,R)-(salen)Co(III)(OAc); boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; water; 1: Jacobsen hydrolytic kinetic resolution / 5: Jacobsen hydrolytic kinetic resolution;
DOI:10.1016/j.tetlet.2007.01.056

Reference yield:

: 1588-44-9
6-phenyl-1-hexene

: 934473-37-7
tert-butyl-{4-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-[2-(4-methoxy-benzyloxy)-ethyl]-but-2-enyloxy}-dimethyl-silane

Guidance literature:: Multi-step reaction with 11 steps

1: 95 percent / m-CPBA / CH₂Cl₂ / 20 °C

2: 42 percent / (R,R)-(salen)Co(III)(OAc) / H₂O

3: 71 percent / CuI / tetrahydrofuran / 20 °C

4: 92 percent / imidazole / CH₂Cl₂ / 20 °C

5: 96 percent / m-CPBA / CH₂Cl₂ / 20 °C

6: 41 percent / (S,S)-(salen)Co(III)(OAc) / H₂O

7: 72 percent / n-BuLi; BF₃*OEt₂ / tetrahydrofuran / -78 °C

8: 87 percent / TBAF / tetrahydrofuran / 20 °C

9: 95 percent / PTSA / CH₂Cl₂ / 20 °C

10: 85 percent / LAH / tetrahydrofuran / 20 °C

11: 98 percent / imidazole / CH₂Cl₂ / 20 °C

With 1H-imidazole; copper(l) iodide; lithium aluminium tetrahydride; (S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate; n-butyllithium; (R,R)-(salen)Co(III)(OAc); boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; water; 2: Jacobsen hydrolytic kinetic resolution / 6: Jacobsen hydrolytic kinetic resolution;
DOI:10.1016/j.tetlet.2007.01.056