gallium hydrogen dichloride

Base Information

• Chemical Name: gallium hydrogen dichloride
• CAS No.: 13886-65-2
• Molecular Formula: Cl₂GaH
• Molecular Weight: 141.637
• Mol file: 13886-65-2.mol

Synonyms:gallium hydrogen dichloride

Chemical Property of gallium hydrogen dichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of gallium hydrogen dichloride

There total 1 articles about gallium hydrogen dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bischloro(3-dimethylaminopropyl)gallium → hydrogenchloride (7647-01-0,15364-23-5) + gallium oxide + gallium(III) chloride + gallium hydrogen dichloride (13886-65-2) + hydrogen cyanide (74-90-8)

Guidance literature:

byproducts: CH4, C2H4, propene; high-vacuum thermolysis (55-65°C, E-6 to E-7 mbar); further org. species detected; not isolated (matrix isolation techniques combined with IR monitoring);

DOI:10.1039/a905183j

Reference yield: 91.0%

gallium hydrogen dichloride (13886-65-2) + 1-Phenyl-2-(trimethylsilyl)acetylene (2170-06-1) → [H5C6-CH2-C(SiMe3)(GaCl2)2]2 (1005391-33-2)

Guidance literature:

In hexane; (Ar); a suspn. of HGaCl2 treated with (CH3)3SiC2C6H5 at room temp., refluxed for 15 h; filtered off, washed (n-hexane), recrystd. (toluene); elem. anal.;

DOI:10.1021/ic701928s

Reference yield: 82.0%

gallium hydrogen dichloride (13886-65-2) + 1-Phenyl-2-(trimethylsilyl)acetylene (2170-06-1) → ((C6H5CHC(Si(CH3)3))GaCl2)2 (950696-88-5)

Guidance literature:

In hexane; under Ar; HGaCl2 (small excess) dissolved in n-hexane; treated with soln. of Me3SiC2C6H5 in n-hexane; heated under reflux for 15 h; filtered; filtrate concd.; crystd. at 4°C; elem. anal.;

DOI:10.1021/ic700767a

Downstream raw materials:

(Z)-1-phenylstyrylgallium(III) dichloride

(E)-1-phenylstyrylgallium(III) dichloride

[H₅C₆-CH₂-C(SiMe₃)(GaCl₂)2]2

C₆H₂((CHC(Si(CH₃)3))2GaCl(O(C₂H₅)2))2