(η-C5H5)Mo(CO)3(PPh3)BF4

Base Information

Chemical Name:(η-C5H5)Mo(CO)3(PPh3)BF4
CAS No.:67251-60-9
Molecular Formula:BF₄*C₂₆H₂₀MoO₃P
Molecular Weight:594.161
Hs Code.:

Synonyms:(η-C5H5)Mo(CO)3(PPh3)BF4

Suppliers and Price of (η-C5H5)Mo(CO)3(PPh3)BF4

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (η-C5H5)Mo(CO)3(PPh3)BF4

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (η-C5H5)Mo(CO)3(PPh3)BF4

There total 8 articles about (η-C5H5)Mo(CO)3(PPh3)BF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 12176-06-6
hydrido(tricarbonyl)(cyclopentadienyl)molybdenum

: 341-02-6
trityl tetrafluoroborate

: 67251-60-9
(η-C5H5)Mo(CO)3(PPh3)BF4

: 78833-68-8
(C₅H₅)Mo(CO)2((C₆H₅)3P)2⁽¹⁺⁾*BF₄^(1-)={(C₅H₅)Mo(CO)2((C₆H₅)3P)2}{BF₄}

Guidance literature:: With triphenyl phosphine; In dichloromethane; under N2, 1 equiv of soln. of Ph3CBF4 in CH2Cl2 at -80°C was treated with Mo-complex, 2 equiv of PPh3 was added; soln. added to ether-pentane, scraping and sitting at 5°C for 8 h, ppt. collected, washed with ether, vac. dried;

Reference yield: 54.0%

: 14104-20-2
silver tetrafluoroborate

: (η-C5H5)Mo(CO)2(PPh3)Cl

: 67251-60-9
(η-C5H5)Mo(CO)3(PPh3)BF4

Guidance literature:: With carbon monoxide; In dichloromethane; bubbling CO through soln. of (C5H5)Mo(CO)2(PPh3)Cl at 22-28 °C with stirring, addn. of AgBF4 while stirring continued, further addn. of AgBF4 after 1.5, 2.5 and 3.5 h; after 5 h filtration (Celite), evapn., pptn. by pouring into hexane, filtration, recrystn. from CH2Cl2-hexane (activated charcoal) with chilling to -30 °C ; elem. anal.;

Reference yield: 8.0%

: 80823-53-6
[(C₅H₅)(CO)2(P(C₆H₅)3)Mo]⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)(CO)2(P(C₆H₅)3)Mo]BF₄

: 74-86-2,25067-58-7
acetylene

: 67251-60-9
(η-C5H5)Mo(CO)3(PPh3)BF4

: 78833-68-8
(C₅H₅)Mo(CO)2((C₆H₅)3P)2⁽¹⁺⁾*BF₄^(1-)={(C₅H₅)Mo(CO)2((C₆H₅)3P)2}{BF₄}

: 80849-84-9
Acetylencarbonylcyclopentadienyltriphenylphosphanmolybdaentetrafluoroborat

: [(C₅H₅)(CO)(P(C₆H₅)3)Mo(CCH₂)]⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)(CO)(P(C₆H₅)3)Mo(CCH₂)]BF₄

Guidance literature:: In dichloromethane; byproducts: [(η5-C5H5)Mo(CO)(HCCH)2]BF4; acetylene introduced to borate/CH2Cl2 at -60 - -50°C, stirred for 15 min; hexane added at -45°C, concd., cooled to -25°C, product washed (hexane), dried (20°C, 8 h, high vac.), elem. anal.;
DOI:10.1016/S0022-328X(00)89153-6