anhydro-2,6-diphenyl-1-hydroxy-5-methyl-3-oxopyrazolo<1,2-a>pyrazolium hydroxide

Base Information

• Chemical Name: anhydro-2,6-diphenyl-1-hydroxy-5-methyl-3-oxopyrazolo<1,2-a>pyrazolium hydroxide
• CAS No.: 79815-54-6
• Molecular Formula: C₁₉H₁₄N₂O₂
• Molecular Weight: 302.332
• Mol file: 79815-54-6.mol

Synonyms:anhydro-2,6-diphenyl-1-hydroxy-5-methyl-3-oxopyrazolo<1,2-a>pyrazolium hydroxide

Chemical Property of anhydro-2,6-diphenyl-1-hydroxy-5-methyl-3-oxopyrazolo<1,2-a>pyrazolium hydroxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of anhydro-2,6-diphenyl-1-hydroxy-5-methyl-3-oxopyrazolo<1,2-a>pyrazolium hydroxide

There total 2 articles about anhydro-2,6-diphenyl-1-hydroxy-5-methyl-3-oxopyrazolo<1,2-a>pyrazolium hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

3-Oxo-2-phenylbutanal (63726-68-1) + 3,5-dihydroxy-4-phenylpyrazole (106367-54-8) → anhydro-2,6-diphenyl-1-hydroxy-5-methyl-3-oxopyrazolo<1,2-a>pyrazolium hydroxide (79815-54-6)

Guidance literature:

for 0.0833333h; Heating;

DOI:10.1021/jo00341a023

Reference yield:

diethyl 2-phenylmalonate (83-13-6) → anhydro-2,6-diphenyl-1-hydroxy-5-methyl-3-oxopyrazolo<1,2-a>pyrazolium hydroxide (79815-54-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 70 percent / hydrazine hydrate / 1 h / Heating

2: 52 percent / 0.08 h / Heating

With hydrazine hydrate;

DOI:10.1021/jo00341a023

Reference yield:

morpholine (110-91-8,99108-56-2) + anhydro-2,6-diphenyl-1-hydroxy-5-methyl-3-oxopyrazolo<1,2-a>pyrazolium hydroxide (79815-54-6) → 3-Methyl-4-phenyl-1H-pyrazole (13788-84-6) + α-phenylmalonmorpholide (79815-71-7)

Guidance literature:

In acetonitrile; at 25 ℃; Rate constant;

DOI:10.1021/jo00341a023

upstream raw materials:

3-Oxo-2-phenylbutanal

3,5-dihydroxy-4-phenylpyrazole

diethyl 2-phenylmalonate

Downstream raw materials:

3-Methyl-4-phenyl-1H-pyrazole

α-phenylmalonmorpholide