Pt(C₂H₄)(1,3-bis(diphenylphosphino)propane)

Base Information

• Chemical Name: Pt(C₂H₄)(1,3-bis(diphenylphosphino)propane)
• CAS No.: 114455-47-9
• Molecular Formula: C₂₉H₃₀P₂Pt
• Molecular Weight: 635.585
• Mol file: 114455-47-9.mol

Synonyms:Pt(C₂H₄)(1,3-bis(diphenylphosphino)propane)

Chemical Property of Pt(C₂H₄)(1,3-bis(diphenylphosphino)propane)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pt(C₂H₄)(1,3-bis(diphenylphosphino)propane)

There total 5 articles about Pt(C₂H₄)(1,3-bis(diphenylphosphino)propane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

cis-PtH2(1,3-bis(diphenylphosphino)propane) (114441-14-4) + ethene (74-85-1) → Pt(C2H4)(1,3-bis(diphenylphosphino)propane) (114455-47-9) + ethane (74-84-0)

Guidance literature:

In diethyl ether; dichloromethane; a 1/1 mixture of EtOH/CH2Cl2 is saturated with ethylene at -78°C; Pt-complex added; stirred at room temp. for 1 h;; filtered; washed with hexane; dried in vacuo; elem. anal.;;

DOI:10.1016/S0020-1693(00)81556-X

Reference yield: 5.0%

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) (59329-00-9) → Pt(C2H4)(1,3-bis(diphenylphosphino)propane) (114455-47-9) + Pt2(o-C6H4P(Ph)(CH2)3PPh2)2

Guidance literature:

With NaBH₄; In ethanol; dichloromethane; under N2, C2H4 passed through a slurry of Pt-compd. in CH2Cl2/EtOH for 15 min with cooling to 10°C, 5 equiv. NaBH4 added in small portions over 30 min with very slowly bubbling of C2H4, C2H4 bubbled through for another 15 min; EtOH added, filtered, stand overnight, after 12 h crystals sept., elem. anal.;

DOI:10.1016/S0020-1693(00)85313-X

Reference yield:

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) (59329-00-9) + ethene (74-85-1) → Pt(C2H4)(1,3-bis(diphenylphosphino)propane) (114455-47-9) + platinum bis(diphenylphosphino)propane (54206-19-8)

Guidance literature:

With Na(Np); In tetrahydrofuran;

DOI:10.1002/(sici)1521-3749(199803)624:3<501::aid-zaac501>3.0.co;2-u

upstream raw materials:

cis-PtH₂(1,3-bis(diphenylphosphino)propane)

ethene

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II)

1,3-bis-(diphenylphosphino)propane

Downstream raw materials:

[(1,3-bis(diphenylphosphino)propane)2Pt2((1,2-η2):(3,4-η2)-2,4-hexadiyne)]

[Pt(η2-methylenecyclopropane)(1,3-bis(diphenylphosphino)propane)]

[Pt(η2-bicyclopropylidene)(1,3-bis(diphenylphosphino)propane)]

[Pt(η2-allylidenecyclopropane)(1,3-bis(diphenylphosphino)propane)]