3-Bromo-2-hydroxyphenyl boronic acid

Base Information

Chemical Name:3-Bromo-2-hydroxyphenyl boronic acid
CAS No.:89488-24-4
Molecular Formula:C6H6 B Br O3
Molecular Weight:216.827
Hs Code.:
Mol file:89488-24-4.mol

Synonyms:3-Bromo-2-hydroxyphenyl boronic acid

Suppliers and Price of 3-Bromo-2-hydroxyphenyl boronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

AOBChem
3-Bromo-2-hydroxyphenylboronicacid 95%
10g
$ 436.00

American Custom Chemicals Corporation
3-BROMO-2-HYDROXYPHENYL BORONIC ACID 95.00%
5MG
$ 499.58

Alichem
3-Bromo-2-hydroxyphenylboronicacid
1g
$ 1519.80

Alichem
3-Bromo-2-hydroxyphenylboronicacid
500mg
$ 782.40

Alichem
3-Bromo-2-hydroxyphenylboronicacid
250mg
$ 504.00

Total 22 raw suppliers

Chemical Property of 3-Bromo-2-hydroxyphenyl boronic acid

Chemical Property:

PSA：60.69000
LogP:-0.16550

Purity/Quality:

98% ^*data from raw suppliers

3-Bromo-2-hydroxyphenylboronicacid 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 3-Bromo-2-hydroxyphenyl boronic acid

There total 4 articles about 3-Bromo-2-hydroxyphenyl boronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 121-43-7,63156-11-6
Trimethyl borate

: 608-33-3
2,6-dibromophenol

: 89488-24-4
(3-bromo-2-hydroxyphenyl)boronic acid

Guidance literature:: 2,6-dibromophenol; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

Trimethyl borate; In tetrahydrofuran; hexane; for 2h;

Reference yield:

: 1431330-19-6
[3-bromo-2-(methoxymethoxy)phenyl]boronic acid

: 89488-24-4
(3-bromo-2-hydroxyphenyl)boronic acid

Guidance literature:: With chloro-trimethyl-silane; sodium iodide; In acetonitrile; at 0 - 20 ℃;
DOI:10.1016/j.tet.2013.03.016

Reference yield:

: 608-33-3
2,6-dibromophenol

: 89488-24-4
(3-bromo-2-hydroxyphenyl)boronic acid

Guidance literature:: Multi-step reaction with 3 steps

1.1: triethylamine / dichloromethane / 7 h / 0 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

2.2: -78 - 20 °C / Inert atmosphere

3.1: sodium iodide; chloro-trimethyl-silane / acetonitrile / 0 - 20 °C

With n-butyllithium; chloro-trimethyl-silane; triethylamine; sodium iodide; In tetrahydrofuran; hexane; dichloromethane; acetonitrile;
DOI:10.1016/j.tet.2013.03.016