C₁₁H₁₈OSi

Base Information

• Chemical Name: C₁₁H₁₈OSi
• CAS No.: 477191-90-5
• Molecular Formula: C₁₁H₁₈OSi
• Molecular Weight: 194.349
• Mol file: 477191-90-5.mol

Synonyms:C₁₁H₁₈OSi

Chemical Property of C₁₁H₁₈OSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of C₁₁H₁₈OSi

There total 1 articles about C₁₁H₁₈OSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

chloro-trimethyl-silane (75-77-4) + 1-chloro-4-methoxy-2-methylbenzene (13334-71-9) → C11H18OSi (477191-90-5)

Guidance literature:

With magnesium; In tetrahydrofuran; for 12h; Heating;

DOI:10.1021/ol026494h

Reference yield: 68.0%

C11H18OSi (477191-90-5) → 3-methyl-4-trimethylsilanyl-phenol (17876-96-9)

Guidance literature:

With potassium hydroxide; In tetrahydrofuran; for 24h; Heating;

DOI:10.1021/ol026494h

Reference yield:

C11H18OSi (477191-90-5) → C10H15(2)HSi (477191-85-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 68 percent / KOH / tetrahydrofuran / 24 h / Heating

2: 62 percent / NEt₃ / 0 - 20 °C

3: 81 percent / Bu₃SnD; dppp / Pd(PPh₃)4 / dimethylformamide / 3 h / 70 °C

With potassium hydroxide; 1,3-bis-(diphenylphosphino)propane; tributyltin deuteride; triethylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; N,N-dimethyl-formamide;

DOI:10.1021/ol026494h

upstream raw materials:

chloro-trimethyl-silane

1-chloro-4-methoxy-2-methylbenzene

Downstream raw materials:

3-methyl-4-trimethylsilanyl-phenol

C₁₀H₁₅⁽²⁾HSi

C₁₀H₁₄⁽²⁾HBrSi

trifluoro-methanesulfonic acid 3-methyl-4-trimethylsilanyl-phenyl ester

Refernces