geranyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldimethylsilyl-β-D-glucopyranoside

Base Information

• Chemical Name: geranyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldimethylsilyl-β-D-glucopyranoside
• CAS No.: 891784-74-0
• Molecular Formula: C₄₃H₅₄O₉Si
• Molecular Weight: 742.982
• Mol file: 891784-74-0.mol

Synonyms:geranyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldimethylsilyl-β-D-glucopyranoside

Chemical Property of geranyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldimethylsilyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of geranyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldimethylsilyl-β-D-glucopyranoside

There total 4 articles about geranyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldimethylsilyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

geranyl 6-O-tert-butyldimethylsilyl-β-D-glucopyranoside (891784-73-9) + benzoyl chloride (98-88-4) → geranyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldimethylsilyl-β-D-glucopyranoside (891784-74-0)

Guidance literature:

In pyridine; at 20 ℃; for 12h;

DOI:10.3987/COM-05-10640

Reference yield:

D-Glucose (2280-44-6) → geranyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldimethylsilyl-β-D-glucopyranoside (891784-74-0)

Guidance literature:

Multi-step reaction with 3 steps

1: 11 percent / immobilized β-D-glucosidase / H2O / 96 h / 50 °C

2: 63 percent / DMAP / pyridine / 24 h / 20 °C

3: 71 percent / pyridine / 12 h / 20 °C

With dmap; immobilized β-D-glucosidase; In pyridine; water;

DOI:10.3987/COM-05-10640

Reference yield:

Geraniol (106-24-1) → geranyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldimethylsilyl-β-D-glucopyranoside (891784-74-0)

Guidance literature:

Multi-step reaction with 3 steps

1: 11 percent / immobilized β-D-glucosidase / H2O / 96 h / 50 °C

2: 63 percent / DMAP / pyridine / 24 h / 20 °C

3: 71 percent / pyridine / 12 h / 20 °C

With dmap; immobilized β-D-glucosidase; In pyridine; water;

DOI:10.3987/COM-05-10640

upstream raw materials:

geranyl 6-O-tert-butyldimethylsilyl-β-D-glucopyranoside

benzoyl chloride

D-Glucose

Geraniol

Downstream raw materials:

geranyl 2,3,4-tri-O-benzoyl-β-D-glucopyranoside

geranyl 6-O-β-D-xylopyranosyl-β-D-glucopyranoside

geraniol-1-O-α-L-arabinopyranosyl-(1->6)-β-D-glucopyranoside

geranyl 2,3,4,2',3',4'-O-hexabenzoyl-β-D-xylopyranosyl-(1->6)-β-D-glucopyranoside