ruthenium3(carbonyl)9(μ3-carbonyl)(μ3-sulfido)

Base Information

• Chemical Name: ruthenium3(carbonyl)9(μ3-carbonyl)(μ3-sulfido)
• CAS No.: 105121-22-0
• Molecular Formula: C₁₀O₁₀Ru₃S
• Molecular Weight: 615.38
• Mol file: 105121-22-0.mol

Synonyms:ruthenium3(carbonyl)9(μ3-carbonyl)(μ3-sulfido)

Chemical Property of ruthenium3(carbonyl)9(μ3-carbonyl)(μ3-sulfido)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ruthenium3(carbonyl)9(μ3-carbonyl)(μ3-sulfido)

There total 2 articles about ruthenium3(carbonyl)9(μ3-carbonyl)(μ3-sulfido) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

Ru3H(1+)*10CO*SC6H5(1-)=HRu3(CO)10(SC6H5) → dodecacarbonyl-triangulo-triruthenium (15243-33-1) + ruthenium3(carbonyl)9(μ3-carbonyl)(μ3-sulfido) (105121-22-0)

Guidance literature:

With CO; In hexane; refluxing (30 min, bubbling CO); crystn., solvent removal (vac.), dissoln. in CH2Cl2, thin layer chromy.(SiO2, hexane); elem. anal.;

Reference yield: 63.0%

(ruthenium)5(carbonyl)11(μ-carbonyl)4(μ4-sulfido) (111976-49-9) → dodecacarbonyl-triangulo-triruthenium (15243-33-1) + Ru6(CO)18(μ4-S) + (ruthenium)7(carbonyl)19(μ-carbonyl)2(μ4-sulfido) (111976-48-8) + ruthenium3(carbonyl)9(μ3-carbonyl)(μ3-sulfido) (105121-22-0)

Guidance literature:

With CO; In n-heptane; Heating to 98°C for 1 h under a slow purge with CO.;

Reference yield: 62.0%

ruthenium pentacarbonyl (16406-48-7) + ruthenium3(carbonyl)9(μ3-carbonyl)(μ3-sulfido) (105121-22-0) → dodecacarbonyl-triangulo-triruthenium (15243-33-1) + Ru6(CO)18(μ4-S) + (ruthenium)5(carbonyl)11(μ-carbonyl)4(μ4-sulfido) (111976-49-9)

Guidance literature:

With CO; In hexane; Addn. of Ru3-complex to soln. of Ru(CO)5, heating to reflux under continuous purge with CO for 10 min, yellow soln. turns brown.; Concg., column chromy. (Florisil), eluation of Ru3(CO)12 with hexane, hexane/CH2Cl2 eluates Ru5-complex (elem. anal.) and later Ru6-complex.;

upstream raw materials:

(ruthenium)5(carbonyl)11(μ-carbonyl)4(μ4-sulfido)

Downstream raw materials:

dodecacarbonyl-triangulo-triruthenium

Ru4(CO)9(μ-CO)2(μ4-S)2

(ruthenium)7(carbonyl)19(μ-carbonyl)2(μ4-sulfido)

(ruthenium)5(carbonyl)11(μ-carbonyl)4(μ4-sulfido)

Refernces

• 1、 Adams, Richard D.,Babin, James E.,Tasi, Miklos. "Cluster syntheses. 13. Chemistry of sulfidoruthenium carbonyl clusters. Synthesis and characterization of the new unsaturated clusters Ru4(CO)11-nLn(μ4-S)2 (n = 0-2, L = PMe2Ph)". . p. 4514 - 4519. Retrieved 2008/10/08.