CID 11053793

Base Information

• Chemical Name: CID 11053793
• CAS No.: 16406-48-7
• Molecular Formula: C₅O₅Ru
• Molecular Weight: 241.122
• Wikidata: Q4348642
• Mol file: 16406-48-7.mol

Synonyms:Q4348642

Chemical Property of CID 11053793

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 241.878913
• Heavy Atom Count: 11
• Complexity: 10

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru]

Technology Process of CID 11053793

There total 21 articles about CID 11053793 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

H3Ru3(μ3-methoxymethylidyne)(carbonyl)9 (71562-47-5) → dodecacarbonyl-triangulo-triruthenium (15243-33-1) + ruthenium pentacarbonyl (16406-48-7) + Dimethyl ether (115-10-6,157621-61-9)

Guidance literature:

With carbon monoxide; hydrogen; In toluene; an autoclave containing a soln. of Ru3-cluster in toluene was pressurized to 500 psig with 1:1 CO-H2 and was heated at 130°C for 23 h; cooled, gases were vented through U-trap (liq. N2), condensate was shown to be Me2O and Ru(CO)5 by mass spectrometry, toluene soln. was filtered (ppt. - Ru3(CO)12 identified by IR data), filtrate evapd., residue chromd. on SiO2 to give addnl. Ru3(CO)12;

DOI:10.1021/om00074a003

Reference yield: 10.0%

H3Ru3(μ3-methoxymethylidyne)(carbonyl)9 (71562-47-5) → 1,2-dimethoxyethane (110-71-4) + dodecacarbonyl-triangulo-triruthenium (15243-33-1) + ruthenium pentacarbonyl (16406-48-7) + Dimethyl ether (115-10-6,157621-61-9) + Methyl formate (107-31-3)

Guidance literature:

With carbon monoxide; hydrogen; In paraffin; an autoclave containing a soln. of Ru3-cluster in parafin oil was pressurized to 500 psig with 1:1 CO-H2 and was heated at 130°C for 23 h; cooled, gases were vented through U-trap cooled by liq. N2, the contentof the trap was analyzed by mass spectrometry;

DOI:10.1021/om00074a003

Reference yield:

HFeRu(CO)5(CH3CCHCHNCH(CH3)2) → iron pentacarbonyl (13463-40-6,37220-42-1) + ruthenium pentacarbonyl (16406-48-7)

Guidance literature:

With CO; In not given; byproducts: MeCH=CHCH=N-i-Pr; inert atmosphere; room temp., 24 h;

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

ruthenium tetracarbonyl

tris(2,4-pentanedionato)ruthenium(III)

carbon monoxide

Downstream raw materials:

dodecacarbonyl-triangulo-triruthenium

Ru7(CO)20(μ4-S)2

Ru6(CO)17(μ4-S)2

((C₆H₅)3P)2N⁽¹⁺⁾*Ru(CO)4(CO₂CH₃)^(1-)=(((C₆H₅)3P)2N)[Ru(CO)4(CO₂CH₃)]