(C₆H₅CH₂)2C₂B₉H₁₁

Base Information

• Chemical Name: (C₆H₅CH₂)2C₂B₉H₁₁
• CAS No.: 769923-89-9
• Molecular Formula: C₁₆H₂₅B₉
• Molecular Weight: 314.673
• Mol file: 769923-89-9.mol

Synonyms:(C₆H₅CH₂)2C₂B₉H₁₁

Chemical Property of (C₆H₅CH₂)2C₂B₉H₁₁

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₆H₅CH₂)2C₂B₉H₁₁

There total 1 articles about (C₆H₅CH₂)2C₂B₉H₁₁ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

[Me3NH][7,8-(C6H5CH2)2-nido-7,8-C2B9H10] + phosphoric acid (86119-84-8,7664-38-2) → (C6H5CH2)2C2B9H11 (769923-89-9)

Guidance literature:

With NaH; In tetrahydrofuran; (N2); standard Schlenk technique; B compd. and NaH were reacted in THF; H3PO4 was added; mixt. was vigorously stirred at room temp. overnight; toluene layer decanted; H3PO4 layer extd. (toluene); toluene soln. combined; dried (MgSO4); solvent removed (vac.); recrystd. (toluene/hexane); elem. anal.;

DOI:10.1021/om049629r

Reference yield: 83.0%

tetrakis(diethylamido)titanium(IV) (4419-47-0) + dichloromethane (75-09-2) + (C6H5CH2)2C2B9H11 (769923-89-9) → [((C6H5CH2)2C2B9H9)Ti(N(C2H5)2)2(NH(C2H5)2)]*CH2Cl2

Guidance literature:

In toluene; (N2); standard Schlenk technique; soln. of B compd. (1 equiv.) in toluene was added with vigorous stirring to soln. of Ti complex (1 equiv.) in toluene at room temp.; mixt. was stirred overnight; solvent removed (vac.); recrystd. (CH2Cl2); elem. anal.;

DOI:10.1021/om049629r

Reference yield: 78.0%

(C6H5CH2)2C2B9H11 (769923-89-9) + Zr(NEt2)4 (943987-58-4) → [((C6H5CH2)2C2B9H9)Zr(N(C2H5)2)2(NH(C2H5)2)]

Guidance literature:

In toluene; (N2); standard Schlenk technique; soln. of B compd. (1 equiv.) in toluene was added with vigorous stirring to soln. of Zr complex (1 equiv.) in toluene at room temp.; mixt. was stirred overnight; solvent removed (vac.); recrystd. (CH2Cl2); elem. anal.;

DOI:10.1021/om049629r

upstream raw materials:

phosphoric acid