cis-diiodo[1,1'-(propane-1,3-diyl)bis[1,1-diphenylphosphine-κP]]platinum

Base Information

• Chemical Name: cis-diiodo[1,1'-(propane-1,3-diyl)bis[1,1-diphenylphosphine-κP]]platinum
• CAS No.: 74429-98-4
• Molecular Formula: C₂₇H₂₆I₂P₂Pt
• Molecular Weight: 861.34
• Mol file: 74429-98-4.mol

Synonyms:cis-diiodo[1,1'-(propane-1,3-diyl)bis[1,1-diphenylphosphine-κP]]platinum

Chemical Property of cis-diiodo[1,1'-(propane-1,3-diyl)bis[1,1-diphenylphosphine-κP]]platinum

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-diiodo[1,1'-(propane-1,3-diyl)bis[1,1-diphenylphosphine-κP]]platinum

There total 6 articles about cis-diiodo[1,1'-(propane-1,3-diyl)bis[1,1-diphenylphosphine-κP]]platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) (59329-00-9) + potassium iodide (7681-11-0) → cis-diiodo[1,1'-(propane-1,3-diyl)bis[1,1-diphenylphosphine-κP]]platinum (74429-98-4)

Guidance literature:

In acetone; to soln. of platinum complex in acetone was added KBr, stirred for 24 h; filtered, evapd., crystd. from CH2Cl2/hexane, elem. anal.;

DOI:10.1002/hlca.201100045

Reference yield: 72.0%

[PtRu2(CO)8(dppp)] + iodine (7553-56-2,12190-71-5,8031-47-8) → cis-diiodo[1,1'-(propane-1,3-diyl)bis[1,1-diphenylphosphine-κP]]platinum (74429-98-4)

Guidance literature:

In dichloromethane; at 20 ℃; for 6h; Inert atmosphere; Schlenk technique;

DOI:10.1080/00958972.2015.1018197

Reference yield: 72.0%

tin(II) iodide + [1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) (59329-00-9) → cis-diiodo[1,1'-(propane-1,3-diyl)bis[1,1-diphenylphosphine-κP]]platinum (74429-98-4)

Guidance literature:

In tetrahydrofuran; dichloromethane; to soln. of platinum complex in CH2Cl2 was added to soln. of SnI2 in THF, stirred for 4 h; evapd., crystd. from CH2Cl2/hexane;

DOI:10.1002/hlca.201100045

upstream raw materials:

(Pt(P(C₆H₅)2)2CH₂CH₂CH₂(SC₄H₂(SC₄(CH₂CH₂CH₂CH₃)2(CC))2))2

iodine

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II)

potassium iodide

Downstream raw materials:

cis-Pt(2,6-dimethylbenzenethiolato-κ1S)2(1,3-bis(diphenylphosphino)propane)

Pt[SC6H3(CH2-2)(Me-6)-κ2S,C](1,3-bis(diphenylphosphino)propane)