¹³C-formate

Base Information

• Chemical Name: ¹³C-formate
• CAS No.: 105959-50-0
• Molecular Formula: CHO₂
• Molecular Weight: 46.0067
• Mol file: 105959-50-0.mol

Synonyms:¹³C-formate

Chemical Property of ¹³C-formate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ¹³C-formate

There total 5 articles about ¹³C-formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-[(13)C]-octadecanal (1276692-89-7) → hepatdecane (629-78-7) + 13C-formate (105959-50-0)

Guidance literature:

With ferredoxin reductase; affinity-tagged Nostoc punctiforme aldehyde decarbonylase; water; NADP; at 23 ℃; for 20h; pH=7.4; HEPES buffer; Enzymatic reaction;

DOI:10.1021/ja2013517

Reference yield:

carbon dioxide (1111-72-4) → [1,2-13C2]acetaldehyde (1632-98-0) + 13C-formate (105959-50-0) + <1,2-13C2>acetate

Guidance literature:

With water; potassium hydrogencarbonate; Electrochemical reaction;

DOI:10.1002/anie.201905318

Reference yield:

methane (6532-48-5) → [13C]methanol (14742-26-8) + 13C-formate (105959-50-0)

Guidance literature:

With [Cu(N,N,N',N'-tetramethylethylenediamine)(OSi(OtBu)₃)₂] supported on alumina; at 200 ℃; for 0.5h; under 2775.28 - 4500.45 Torr; Inert atmosphere;

DOI:10.1002/anie.201903802

upstream raw materials:

1-[⁽¹³⁾C]-octadecanal

carbon dioxide

methane

Refernces

• 1、 Xiang, Dongmei,Magana, Donny,Dyer, R. Brian. "CO2 reduction catalyzed by mercaptopteridine on glassy carbon". . p. 14007 - 14010. Retrieved 2014.
• 2、 Li, Ning,Norgaard, Hanne,Warui, Douglas M.,Booker, Squire J.,Krebs, Carsten,Bollinger, J. Martin. "Conversion of fatty aldehydes to alka(e)nes and formate by a cyanobacterial aldehyde decarbonylase: Cryptic redox by an unusual dimetal oxygenase". . p. 6158 - 6161. Retrieved 2011.
• 3、 Kuramochi, Yusuke,Sekine, Masato,Kitamura, Kyohei,Maegawa, Yoshifumi,Goto, Yasutomo,Shirai, Soichi,Inagaki, Shinji,Ishida, Hitoshi. "Photocatalytic CO2 Reduction by Periodic Mesoporous Organosilica (PMO) Containing Two Different Ruthenium Complexes as Photosensitizing and Catalytic Sites". . p. 10301 - 10309. Retrieved 2017.
• 4、 Back, Changhyun,Seo, Yunjeong,Choi, Sunghan,Choe, Min Su,Lee, Daehan,Baeg, Jin-Ook,Son, Ho-Jin,Kang, Sang Ook. "Secondary Coordination Effect on Monobipyridyl Ru(II) Catalysts in Photochemical CO2Reduction: Effective Proton Shuttle of Pendant Br?nsted Acid/Base Sites (OH and N(CH3)2) and Its Mechanistic Investigation". . p. 14151 - 14164. Retrieved 2021/09/20.