Carbon-13

Base Information

• Chemical Name: Carbon-13
• CAS No.: 6532-48-5
• Molecular Formula: CH4
• Molecular Weight: 17.0318
• European Community (EC) Number: 620-574-1,628-406-9
• UNII: FDJ0A8596D
• DSSTox Substance ID: DTXSID20912297
• Nikkaji Number: J840.825D,J866.220G,J910.565D
• Wikidata: Q1770822
• Mol file: 6532-48-5.mol

Synonyms:13C isotope;C-13 isotope;Carbon-13

Chemical Property of Carbon-13

Chemical Property:

• Melting Point: −183 °C(lit.)
• Boiling Point: −161 °C(lit.)
• Flash Point: -188℃
• PSA: 0.00000
• Density: 0.55 (vs air)
• LogP: 0.63610
• XLogP3: 0.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 17.034654963
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Methane-13C 99 atom % ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F+
• Statements: 12
• Safety Statements: 16-38

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C
• Isomeric SMILES: [13CH4]

Technology Process of Carbon-13

There total 19 articles about Carbon-13 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[13C]methanol (14742-26-8) + carbon monoxide (201230-82-2) → methane (6532-48-5) + formyl radical (2597-44-6) + [13C]-formaldehyde (3228-27-1,89277-65-6) + [1,2-13C2]-glycolaldehyde (478529-69-0,478529-67-8) + (13C)-methyl formate + carbon dioxide (1111-72-4)

Guidance literature:

at -267.66 - 26.84 ℃; Irradiation;

DOI:10.1039/c4cp04149f

Reference yield:

[13C]methanol (14742-26-8) → methane (6532-48-5) + [13C]-formaldehyde (3228-27-1,89277-65-6) + [1,2-13C2]-glycolaldehyde (478529-69-0,478529-67-8) + ketene + (13C)-methyl formate + carbon dioxide (1111-72-4) + [13C]Carbon monoxide (1641-69-6) + ethylene glycol-13C2 (104700-12-1) + 13C-carbon monoxide + (13)CH2OH

Guidance literature:

at -267.66 - 26.84 ℃; Irradiation;

DOI:10.1039/c4cp04149f

Reference yield:

carbon dioxide (1111-72-4) + water-d2 (7789-20-0) → methane (6532-48-5) + methane (558-20-3) + [13C]Carbon monoxide (1641-69-6)

Guidance literature:

With amorphous boron powder; Irradiation;

DOI:10.1002/anie.201701370

upstream raw materials:

¹³C-2-propane

ethane-¹³C₁

[13C]Carbon monoxide

[¹³C]methanol

Downstream raw materials:

1-(13)C-n-butane

(1-13C)Propane

Isobutane

1-fluoroethane