ethyl 3-(p-toylthio)acrylate

Base Information

Chemical Name:ethyl 3-(p-toylthio)acrylate
CAS No.:1138-92-7
Molecular Formula:C₁₂H₁₄O₂S
Molecular Weight:222.308
Hs Code.:

Synonyms:ethyl 3-(p-toylthio)acrylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ethyl 3-(p-toylthio)acrylate

Chemical Property:

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Technology Process of ethyl 3-(p-toylthio)acrylate

There total 6 articles about ethyl 3-(p-toylthio)acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 108990-03-0
p-tolylsulfanylpropynoic acid ethyl ester

: 1138-92-7
(Z)-ethyl 3-(p-tolylsulfanyl)acrylate

Guidance literature:: p-tolylsulfanylpropynoic acid ethyl ester; With triphenylphosphine; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; copper(l) chloride; sodium t-butanolate; In tetrahydrofuran; at 0 ℃;

With methanol; In tetrahydrofuran; at 60 ℃; for 1h; diastereoselective reaction;
DOI:10.1002/ejoc.201801181

Reference yield: 69.7%

: 105-37-3,20741-13-3
Ethyl propionate

: 106-45-6
para-thiocresol

: 1138-92-7
ethyl (E)-3-(p-tolylthio)acrylate

Guidance literature:: In tetrahydrofuran; at 65 ℃; for 1h;
DOI:10.1002/ardp.201600307

Reference yield:

: 106-45-6
para-thiocresol

: 623-47-2
propynoic acid ethyl ester

: 1138-92-7
(Z)-ethyl 3-(p-tolylsulfanyl)acrylate

: 1138-92-7
ethyl (E)-3-(p-tolylthio)acrylate

Guidance literature:: para-thiocresol; With N-ethyl-N,N-diisopropylamine; In dichloromethane; at -78 ℃; for 0.25h; Inert atmosphere;

propynoic acid ethyl ester; In dichloromethane; at -78 ℃; for 1h; Overall yield = 93 %; Overall yield = 413 mg; diastereoselective reaction; Inert atmosphere;
DOI:10.1016/j.tetlet.2012.08.051