[Ir(5,10,15,20-tetra-p-tolylporphyrinato dianion)(4-fluorophenyl)]

Base Information

• Chemical Name: [Ir(5,10,15,20-tetra-p-tolylporphyrinato dianion)(4-fluorophenyl)]
• CAS No.: 1280227-56-6
• Molecular Formula: C₅₄H₄₁FIrN₄
• Molecular Weight: 957.165
• Mol file: 1280227-56-6.mol

Synonyms:[Ir(5,10,15,20-tetra-p-tolylporphyrinato dianion)(4-fluorophenyl)]

Chemical Property of [Ir(5,10,15,20-tetra-p-tolylporphyrinato dianion)(4-fluorophenyl)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ir(5,10,15,20-tetra-p-tolylporphyrinato dianion)(4-fluorophenyl)]

There total 13 articles about [Ir(5,10,15,20-tetra-p-tolylporphyrinato dianion)(4-fluorophenyl)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride (872415-81-1) + 1-Bromo-4-fluorobenzene (460-00-4) → (p-fluorophenyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (1280227-56-6)

Guidance literature:

With K₂CO₃; In benzene; mixing Ir complex, Br compd., K2CO3 (20 equiv.), C6H6, 200°C, 20 h;

DOI:10.1021/om200027q

Reference yield: 96.0%

(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride (872415-81-1) + 4-fluoro-1-iodobenzene (352-34-1) → (p-fluorophenyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (1280227-56-6)

Guidance literature:

With NaOH; In benzene; Ir-complex, NaOH, 1-fluoro-4-iodobenzene and benzene were heated in a Teflon-screw-capped tube at 150°C under N2 for 1 d; column chromy. over alumina with CH2Cl2/hexane (1/2);

DOI:10.1021/om200251k

Reference yield: 90.0%

(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride (872415-81-1) + 1-Bromo-4-fluorobenzene (460-00-4) → [Ir(5,10,15,20-tetra-p-tolylporphyrinato dianion)(4-fluorophenyl)] (1280227-56-6)

Guidance literature:

With potassium hydroxide; In benzene; at 200 ℃; for 6h; Solvent; Inert atmosphere;

DOI:10.1021/om301196t

upstream raw materials:

(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride

1-Bromo-4-fluorobenzene

4-fluoro-1-iodobenzene

iodobenzene

Downstream raw materials:

phenyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

fluorobenzene

Ir(ttp)C₆D₆