Technology Process of C26H37NO4Si
There total 4 articles about C26H37NO4Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
dimethyl amine;
With
trimethylaluminum;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 0.5h;
Inert atmosphere;
C24H30O4Si;
In
tetrahydrofuran; hexane;
at 0 - 20 ℃;
for 1.5h;
Inert atmosphere;
DOI:10.1021/ol501446w
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: N-iodo-succinimide; tetra-(n-butyl)ammonium iodide / dichloromethane / 21 h / 20 °C / Inert atmosphere
2.1: dmap / acetonitrile / 0.67 h / 0 °C / Inert atmosphere
3.1: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / toluene / 0.5 h / Inert atmosphere; Reflux
4.1: trimethylaluminum / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere
4.2: 1.5 h / 0 - 20 °C / Inert atmosphere
With
dmap; N-iodo-succinimide; 2,2'-azobis(isobutyronitrile); trimethylaluminum; tri-n-butyl-tin hydride; tetra-(n-butyl)ammonium iodide;
In
tetrahydrofuran; hexane; dichloromethane; toluene; acetonitrile;
3.1: |Barton-McCombie Deoxygenation;
DOI:10.1021/ol501446w
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / toluene / 0.5 h / Inert atmosphere; Reflux
2.1: trimethylaluminum / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere
2.2: 1.5 h / 0 - 20 °C / Inert atmosphere
With
2,2'-azobis(isobutyronitrile); trimethylaluminum; tri-n-butyl-tin hydride;
In
tetrahydrofuran; hexane; toluene;
1.1: |Barton-McCombie Deoxygenation;
DOI:10.1021/ol501446w
