Ru(hexyl-picnic-basket porphyrin)(1,5-dicyclohexylimidazole)out(Cl)in*0.5CHCl₃

Base Information

Chemical Name:Ru(hexyl-picnic-basket porphyrin)(1,5-dicyclohexylimidazole)out(Cl)in*0.5CHCl₃
CAS No.:113585-22-1
Molecular Formula:0CHCl₃*C₈₁H₇₀ClN₁₀O₆Ru
Molecular Weight:1475.72
Hs Code.:

Ru(hexyl-picnic-basket porphyrin)(1,5-dicyclohexylimidazole)out(Cl)in*0.5CHCl<sub>3</sub>

Synonyms:Ru(hexyl-picnic-basket porphyrin)(1,5-dicyclohexylimidazole)out(Cl)in*0.5CHCl₃

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ru(hexyl-picnic-basket porphyrin)(1,5-dicyclohexylimidazole)out(Cl)in*0.5CHCl₃

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Technology Process of Ru(hexyl-picnic-basket porphyrin)(1,5-dicyclohexylimidazole)out(Cl)in*0.5CHCl₃

There total 1 articles about Ru(hexyl-picnic-basket porphyrin)(1,5-dicyclohexylimidazole)out(Cl)in*0.5CHCl₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 113585-19-6
Ru(hexyl-picnic-basket porphyrin)(1,5-dicyclohexylimidazole)out(tetrahydrofurane)in

: 56-34-8
tetraethylammonium chloride

: 80964-44-9
1,5-dicyclohexyl imidazole

: 113585-22-1
Ru(hexyl-picnic-basket porphyrin)(1,5-dicyclohexylimidazole)out(Cl)in*0.5CHCl₃

Guidance literature:: With AgBF₄; In tetrahydrofuran; toluene; inert atmosphere; AgBF4 added to soln. of Ru-compound/1,5-DCI; stirred (0.5h); filtration (Celite); Ru(III)-complex washed from Celite (20:1 CH2Cl2:THF); evapn. (vacuum); residue dissolved in CH2Cl2 contg. Et4NCl; stirred (4h); evapn. (rotovap);; residue dissolved (CH2Cl2); chromy. (SiO2, CH2Cl2 to 10/1 CH2Cl2/Et2O solvent gradient); deep red-brown band isolated; evapn.; recrystn. by layering C6H6 on a CHCl3 soln. of the Ru(III)-complex; elem. anal.;
DOI:10.1021/ja00219a024

Reference yield:

: 113585-22-1
Ru(hexyl-picnic-basket porphyrin)(1,5-dicyclohexylimidazole)out(Cl)in*0.5CHCl₃

: 7727-37-9
nitrogen

: 113585-28-7
Ru(hexyl-picnic-basket porphyrin)(1,5-dicyclohexylimidazole)out(N₂)in

Guidance literature:: With Sn; In benzene; inert atmosphere; Ru(III)-complex dissolved in N2-satd. benzene; activated (washed with dilute HCl, dried) Sn added; stirred for 2h;; soln. passed through glass wool plug; dinitrogen complex not isolated;;
DOI:10.1021/ja00219a024