Acetophenone, -alpha-,-alpha--dichloro--alpha--(3,5-dichloro-2-nitrophenyl)-2-nitroso- (4CI)

Base Information

• Chemical Name: Acetophenone, -alpha-,-alpha--dichloro--alpha--(3,5-dichloro-2-nitrophenyl)-2-nitroso- (4CI)
• CAS No.: 873411-82-6
• Molecular Formula: C14H6 Cl4 N2 O4
• Molecular Weight: 408.025
• Mol file: 873411-82-6.mol

Synonyms:Acetophenone,a,a-dichloro-a-(3,5-dichloro-2-nitrophenyl)-2-nitroso- (4CI)

Chemical Property of Acetophenone, -alpha-,-alpha--dichloro--alpha--(3,5-dichloro-2-nitrophenyl)-2-nitroso- (4CI)

Chemical Property:

• PSA: 92.32000
• LogP: 6.33600

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Acetophenone, -alpha-,-alpha--dichloro--alpha--(3,5-dichloro-2-nitrophenyl)-2-nitroso- (4CI)

There total 2 articles about Acetophenone, -alpha-,-alpha--dichloro--alpha--(3,5-dichloro-2-nitrophenyl)-2-nitroso- (4CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,2-bis(2-nitrophenyl)ethyne (25407-11-8) → α,α,3',5'-tetrachloro-2'-nitro-2-nitroso-deoxybenzoin (873411-82-6)

Guidance literature:

With chloroform; chlorine;

DOI:10.1002/hlca.193802101154

Reference yield:

chloroform (67-66-3,8013-54-5) + 1,2-bis(2-nitrophenyl)ethyne (25407-11-8) + chlorine (7782-50-5) → α,α,3',5'-tetrachloro-2'-nitro-2-nitroso-deoxybenzoin (873411-82-6)

Guidance literature:

DOI:10.1002/hlca.193802101154

Reference yield:

α,α,3',5'-tetrachloro-2'-nitro-2-nitroso-deoxybenzoin (873411-82-6) → ortho-nitrobenzoic acid (552-16-9,104810-18-6)

Guidance literature:

Multi-step reaction with 2 steps

1: CrO₃; acetic acid; concentrated nitric acid

2: water containing pyridine

With pyridine; chromium(VI) oxide; nitric acid; acetic acid;

DOI:10.1002/hlca.193802101154

upstream raw materials:

1,2-bis(2-nitrophenyl)ethyne

chloroform

chlorine

Downstream raw materials:

α,α,3',5'-tetrachloro-2,2'-dinitro-deoxybenzoin

ortho-nitrobenzoic acid