(C₆H₅)2P(CH₂)4P(C₆H₅)2*CH₃CN*Pd⁽²⁺⁾*CH₃^(1-)*SO₃CF₃^(1-)={((C₆H₅)2P(CH₂)4P(C₆H₅)2)Pd(CH₃)(CH₃CN)}(SO₃CF₃)

Base Information

• Chemical Name: (C₆H₅)2P(CH₂)4P(C₆H₅)2*CH₃CN*Pd⁽²⁺⁾*CH₃^(1-)*SO₃CF₃^(1-)={((C₆H₅)2P(CH₂)4P(C₆H₅)2)Pd(CH₃)(CH₃CN)}(SO₃CF₃)
• CAS No.: 139168-29-9
• Molecular Formula: CF₃O₃S*CH₃*C₂H₃N*C₂₈H₂₈P₂*Pd
• Molecular Weight: 738.056

Synonyms:(C₆H₅)2P(CH₂)4P(C₆H₅)2*CH₃CN*Pd⁽²⁺⁾*CH₃^(1-)*SO₃CF₃^(1-)={((C₆H₅)2P(CH₂)4P(C₆H₅)2)Pd(CH₃)(CH₃CN)}(SO₃CF₃)

Chemical Property of (C₆H₅)2P(CH₂)4P(C₆H₅)2*CH₃CN*Pd⁽²⁺⁾*CH₃^(1-)*SO₃CF₃^(1-)={((C₆H₅)2P(CH₂)4P(C₆H₅)2)Pd(CH₃)(CH₃CN)}(SO₃CF₃)

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Technology Process of (C₆H₅)2P(CH₂)4P(C₆H₅)2*CH₃CN*Pd⁽²⁺⁾*CH₃^(1-)*SO₃CF₃^(1-)={((C₆H₅)2P(CH₂)4P(C₆H₅)2)Pd(CH₃)(CH₃CN)}(SO₃CF₃)

There total 1 articles about (C₆H₅)2P(CH₂)4P(C₆H₅)2*CH₃CN*Pd⁽²⁺⁾*CH₃^(1-)*SO₃CF₃^(1-)={((C₆H₅)2P(CH₂)4P(C₆H₅)2)Pd(CH₃)(CH₃CN)}(SO₃CF₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

[1,3-bis(diphenylphosphino)propane]Pd-MeCl (139168-07-3) + silver trifluoromethanesulfonate (2923-28-6) → (C6H5)2P(CH2)4P(C6H5)2*CH3CN*Pd(2+)*CH3(1-)*SO3CF3(1-)={((C6H5)2P(CH2)4P(C6H5)2)Pd(CH3)(CH3CN)}(SO3CF3) (139168-29-9)

Guidance literature:

With acetonitrile; In dichloromethane; acetonitrile; byproducts: AgCl; dropwise addn. of AgSO3CF3 in CH3CN to a rapidly stirred soln. of the Pd complex in CH2Cl2/CH3CN (under N2); filtered, filtrate collected in Et2O (-20°C, rapid stirring), ppt. filtered off, washed (benzene, pentane), recrystd. (CH2Cl2/ Et2O); product mixt. of monomeric and oligomeric complexes (NMR) obtained; elem. anal.;

DOI:10.1021/om00040a034

Reference yield:

(C6H5)2P(CH2)4P(C6H5)2*CH3CN*Pd(2+)*CH3(1-)*SO3CF3(1-)={((C6H5)2P(CH2)4P(C6H5)2)Pd(CH3)(CH3CN)}(SO3CF3) (139168-29-9) → (C6H5)2P(CH2)4P(C6H5)2*Pd(2+)*COCH3(1-)*CH3CN*CF3SO3(1-)={((C6H5)2P(CH2)4P(C6H5)2)Pd(COCH3)(CH3CN)}(CF3SO3) (139168-23-3)

Guidance literature:

With carbon monoxide; In chloroform-d1; 1 atm. CO, 5 min., room temp.; isolation was not successfull; detn. by (1)H-, (31)P-NMR, IR;

DOI:10.1021/om00040a034

upstream raw materials:

[1,3-bis(diphenylphosphino)propane]Pd-MeCl

silver trifluoromethanesulfonate

Downstream raw materials:

(C₆H₅)2P(CH₂)4P(C₆H₅)2*Pd⁽²⁺⁾*COCH₃^(1-)*CH₃CN*CF₃SO₃^(1-)={((C₆H₅)2P(CH₂)4P(C₆H₅)2)Pd(COCH₃)(CH₃CN)}(CF₃SO₃)

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