methanesulfonic acid 15-[2-(15-allyloxy-pentadecyloxymethoxymethyl)-benzyloxymethoxy]-pentadecyl ester

Base Information

Chemical Name:methanesulfonic acid 15-[2-(15-allyloxy-pentadecyloxymethoxymethyl)-benzyloxymethoxy]-pentadecyl ester
CAS No.:791805-34-0
Molecular Formula:C₄₄H₈₀O₈S
Molecular Weight:769.18
Hs Code.:

Synonyms:methanesulfonic acid 15-[2-(15-allyloxy-pentadecyloxymethoxymethyl)-benzyloxymethoxy]-pentadecyl ester

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Chemical Property of methanesulfonic acid 15-[2-(15-allyloxy-pentadecyloxymethoxymethyl)-benzyloxymethoxy]-pentadecyl ester

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Technology Process of methanesulfonic acid 15-[2-(15-allyloxy-pentadecyloxymethoxymethyl)-benzyloxymethoxy]-pentadecyl ester

There total 11 articles about methanesulfonic acid 15-[2-(15-allyloxy-pentadecyloxymethoxymethyl)-benzyloxymethoxy]-pentadecyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 124-63-0
methanesulfonyl chloride

: 791805-32-8
15-[2-(15-allyloxy-pentadecyloxymethoxymethyl)-benzyloxymethoxy]-pentadecan-1-ol

: 791805-34-0
methanesulfonic acid 15-[2-(15-allyloxy-pentadecyloxymethoxymethyl)-benzyloxymethoxy]-pentadecyl ester

Guidance literature:: With pyridine; dmap; In dichloromethane; at 20 ℃;
DOI:10.1021/jo0493020

Reference yield:

: 106-02-5,81031-90-5
pentadecanolide

: 791805-34-0
methanesulfonic acid 15-[2-(15-allyloxy-pentadecyloxymethoxymethyl)-benzyloxymethoxy]-pentadecyl ester

Guidance literature:: Multi-step reaction with 9 steps

1.1: 87 percent / Amberlyst A-15 / 48 h / Heating

2.1: chlorotrimethylsilane / CH₂Cl₂ / 1.33 h / 20 °C

3.1: diisopropylethylamine; tetrabutylammonium iodide / tetrahydrofuran / Heating

4.1: 10.7 g / LiAlH₄ / tetrahydrofuran / Heating

5.1: NaH / tetrahydrofuran / 1 h / 0 °C

5.2: 66 percent / tetrabutylammonium iodide / tetrahydrofuran / 4 h / Heating

6.1: 95 percent / Dowex 50WX₈-200 H⁽¹⁺⁾ / tetrahydrofuran; H₂O

7.1: 100 percent / diisopropylethylamine; tetrabutylammonium iodide / tetrahydrofuran / 6 h / Heating

8.1: 80 percent / LiAlH₄ / tetrahydrofuran / Heating

9.1: 90 percent / pyridine; DMAP / CH₂Cl₂ / 20 °C

With pyridine; dmap; lithium aluminium tetrahydride; chloro-trimethyl-silane; Amberlyst A-15; Dowex 50WX₈-200 H⁽¹⁺⁾; tetra-(n-butyl)ammonium iodide; sodium hydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/jo0493020

Reference yield:

: 76529-42-5
methyl 15-hydroxypentadecanoate

: 791805-34-0
methanesulfonic acid 15-[2-(15-allyloxy-pentadecyloxymethoxymethyl)-benzyloxymethoxy]-pentadecyl ester

Guidance literature:: Multi-step reaction with 8 steps

1.1: chlorotrimethylsilane / CH₂Cl₂ / 1.33 h / 20 °C

2.1: diisopropylethylamine; tetrabutylammonium iodide / tetrahydrofuran / Heating

3.1: 10.7 g / LiAlH₄ / tetrahydrofuran / Heating

4.1: NaH / tetrahydrofuran / 1 h / 0 °C

4.2: 66 percent / tetrabutylammonium iodide / tetrahydrofuran / 4 h / Heating

5.1: 95 percent / Dowex 50WX₈-200 H⁽¹⁺⁾ / tetrahydrofuran; H₂O

6.1: 100 percent / diisopropylethylamine; tetrabutylammonium iodide / tetrahydrofuran / 6 h / Heating

7.1: 80 percent / LiAlH₄ / tetrahydrofuran / Heating

8.1: 90 percent / pyridine; DMAP / CH₂Cl₂ / 20 °C

With pyridine; dmap; lithium aluminium tetrahydride; chloro-trimethyl-silane; Dowex 50WX₈-200 H⁽¹⁺⁾; tetra-(n-butyl)ammonium iodide; sodium hydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/jo0493020