β-<(tert-butyldimethylsilyl)oxy>-δ-hydroxypimelic acid, N-(benzyloxy)amide monomethyl ester

Base Information

Chemical Name:β-<(tert-butyldimethylsilyl)oxy>-δ-hydroxypimelic acid, N-(benzyloxy)amide monomethyl ester
CAS No.:130075-12-6
Molecular Formula:C₂₁H₃₅NO₆Si
Molecular Weight:425.598
Hs Code.:

Synonyms:β-<(tert-butyldimethylsilyl)oxy>-δ-hydroxypimelic acid, N-(benzyloxy)amide monomethyl ester

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Chemical Property of β-<(tert-butyldimethylsilyl)oxy>-δ-hydroxypimelic acid, N-(benzyloxy)amide monomethyl ester

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Technology Process of β-<(tert-butyldimethylsilyl)oxy>-δ-hydroxypimelic acid, N-(benzyloxy)amide monomethyl ester

There total 4 articles about β-<(tert-butyldimethylsilyl)oxy>-δ-hydroxypimelic acid, N-(benzyloxy)amide monomethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 109462-20-6
1-methyl hydrogen 3-<(tert-butyl)dimethylsilyloxy>glutarate

: 130075-12-6
β-<(tert-butyldimethylsilyl)oxy>-δ-hydroxypimelic acid, N-(benzyloxy)amide monomethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1) carbonyldiimidazole / 1) THF, 3 h, r.t., 2) a) 42 h, r.t., b) 24 h, 35 deg C

2: 84 percent / NaBH₄ / methanol / 0.25 h / 0 °C

3: 1) H₂, 2) N-hydroxysuccinimide, dicyclohexylcarbodiimide / 1) 10percent Pd/C

With sodium tetrahydroborate; 1-hydroxy-pyrrolidine-2,5-dione; hydrogen; dicyclohexyl-carbodiimide; 1,1'-carbonyldiimidazole; palladium on activated charcoal; In methanol;
DOI:10.1021/jo00003a066

Reference yield:

: 130075-11-5
β-<(tert-butyldimethylsilyl)oxy>-δ-oxopimelic acid, methyl benzyl diester

: 130075-12-6
β-<(tert-butyldimethylsilyl)oxy>-δ-hydroxypimelic acid, N-(benzyloxy)amide monomethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / NaBH₄ / methanol / 0.25 h / 0 °C

2: 1) H₂, 2) N-hydroxysuccinimide, dicyclohexylcarbodiimide / 1) 10percent Pd/C

With sodium tetrahydroborate; 1-hydroxy-pyrrolidine-2,5-dione; hydrogen; dicyclohexyl-carbodiimide; palladium on activated charcoal; In methanol;
DOI:10.1021/jo00003a066

Reference yield:

: 131352-56-2,131352-57-3,137993-44-3,137993-45-4
β-<(tert-butyldimethylsilyl)oxy>-δ-hydroxypimelic acid, methyl benzyl diester

: 130075-12-6
β-<(tert-butyldimethylsilyl)oxy>-δ-hydroxypimelic acid, N-(benzyloxy)amide monomethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: H₂ / Pd/C

2: DCC

With hydrogen; dicyclohexyl-carbodiimide; palladium on activated charcoal;
DOI:10.1016/S0040-4039(00)98791-4