bis(triphenylphosphine)gold(I) hexafluorophosphate

Base Information

Chemical Name:bis(triphenylphosphine)gold(I) hexafluorophosphate
CAS No.:73872-15-8
Molecular Formula:C₃₆H₃₀AuP₂*F₆P
Molecular Weight:866.512
Hs Code.:

Synonyms:bis(triphenylphosphine)gold(I) hexafluorophosphate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(triphenylphosphine)gold(I) hexafluorophosphate

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Technology Process of bis(triphenylphosphine)gold(I) hexafluorophosphate

There total 10 articles about bis(triphenylphosphine)gold(I) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 754194-75-7
[(gold(I))(6-CH2CMe3-2,2'-bipyridine)(η2-styrene)][PF6]

: 603-35-0
triphenylphosphine

: 73872-15-8
bis(triphenylphosphine)gold(I) hexafluorophosphate

Guidance literature:: In not given; coordinated styrene readly displaced by PPh3; NMR;
DOI:10.1039/b404890c

Reference yield: 97.0%

: 14243-64-2
(triphenylphosphine)gold(I) chloride

: 60969-19-9
thallium(I) hexafluorophosphate

: 603-35-0
triphenylphosphine

: 73872-15-8
bis(triphenylphosphine)gold(I) hexafluorophosphate

Guidance literature:: In dichloromethane; for 1.5h; Darkness;
DOI:10.1016/j.ejmech.2017.12.048

Reference yield: 90.0%

: 17084-13-8
potassium hexafluorophosphate

: 39929-21-0
(tetrahydrothiophene)gold(I) chloride

: 603-35-0
triphenylphosphine

: 73872-15-8
bis(triphenylphosphine)gold(I) hexafluorophosphate

Guidance literature:: In tetrahydrofuran; under N2; PPh3 and KPF6 added to soln. of Au complex in THF; stirred andreflux for 2 h; filtered; concd.; Et2O added with stirring; ppt. washed with ether; dried in vac. for 2 h; crystd. by slow diffusion of hexane into very concd. CH2Cl2 soln. in the dark;
DOI:10.1016/j.jorganchem.2008.10.034