Pd(1-benzyl-2-(naphthyl-α-azo)imidazole)Cl2

Base Information

• Chemical Name: Pd(1-benzyl-2-(naphthyl-α-azo)imidazole)Cl2
• CAS No.: 365221-68-7
• Molecular Formula: C₂₀H₁₆Cl₂N₄Pd
• Molecular Weight: 489.7
• Mol file: 365221-68-7.mol

Synonyms:Pd(1-benzyl-2-(naphthyl-α-azo)imidazole)Cl2

Chemical Property of Pd(1-benzyl-2-(naphthyl-α-azo)imidazole)Cl2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Pd(1-benzyl-2-(naphthyl-α-azo)imidazole)Cl2

There total 1 articles about Pd(1-benzyl-2-(naphthyl-α-azo)imidazole)Cl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

1-benzyl-2-(naphthyl-α-azo)-imidazole (356522-77-5) + palladium dichloride → Pd(1-benzyl-2-(naphthyl-α-azo)imidazole)Cl2 (365221-68-7)

Guidance literature:

In acetonitrile; ligand added to boiling soln. of PdCl2, stirred for 0.5 h; pptd. on slow evapn. in air, filtered, washed (cold MeCN, Et2O), dried (vac.); elem. anal.;

DOI:10.1016/S0022-328X(01)00787-2

Reference yield: 82.0%

Pd(1-benzyl-2-(naphthyl-α-azo)imidazole)Cl2 (365221-68-7) → [Pd(C6H5CH2C3H2N2N2C10H6O)Cl]

Guidance literature:

With air; NaOH; In water; acetonitrile; NaOH/H2O/MeCN added dropwise to Pd complex/MeCN in air, stirred for 24 hat pH 8-10; evapd. (vac.), washed (H2O), dried (P4O10), dissolved in CH2Cl2, chromd.(SiO2, MeCN/C6H6), evapd. (vac.); elem. anal.;

DOI:10.1016/S0022-328X(01)00787-2

Reference yield:

2-Picolinic acid (98-98-6) + Pd(1-benzyl-2-(naphthyl-α-azo)imidazole)Cl2 (365221-68-7) → [Pd(1-benzyl-2-(naphthyl-α-azo)imidazole)(picolinate)](1+) (959986-54-0)

Guidance literature:

With lithium chloride; In acetonitrile; 298 K; Kinetics;

DOI:10.1016/j.poly.2007.06.016

upstream raw materials:

1-benzyl-2-(naphthyl-α-azo)-imidazole

Downstream raw materials:

[Pd(1-benzyl-2-(naphthyl-α-azo)imidazole)(picolinate)](1+)

[Pd(1-benzyl-2-(naphthyl-α-azo)imidazole)(picolinate)]ClO4

Pd(8-quinolinate)(1-benzyl-2-(naphthyl-α-azo)imidazole)