trans-bis(triphenylphosphane)-bis-(4-acetylene)phenyl thioacetate platinum(II)

Base Information

Chemical Name:trans-bis(triphenylphosphane)-bis-(4-acetylene)phenyl thioacetate platinum(II)
CAS No.:442514-12-7
Molecular Formula:C₅₆H₄₄O₂P₂PtS₂
Molecular Weight:1070.12
Hs Code.:

Synonyms:trans-bis(triphenylphosphane)-bis-(4-acetylene)phenyl thioacetate platinum(II)

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Chemical Property of trans-bis(triphenylphosphane)-bis-(4-acetylene)phenyl thioacetate platinum(II)

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Technology Process of trans-bis(triphenylphosphane)-bis-(4-acetylene)phenyl thioacetate platinum(II)

There total 1 articles about trans-bis(triphenylphosphane)-bis-(4-acetylene)phenyl thioacetate platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

: 14056-88-3
trans-dichlorobis(triphenylphosphine)platinum(II)

: 170159-24-7
acetylsulfanyl-4-(ethynyl)benzene

: 442514-12-7
trans-bis(triphenylphosphane)-bis-(4-acetylene)phenyl thioacetate platinum(II)

Guidance literature:: With diisopropylamine; copper(l) iodide; In tetrahydrofuran; dissolving thioacetate deriv. in N2 saturated THF, addn. of platinum complex and CuI followed by diisopropylamine, soln. of mixture stirred at 30°C under N2 atm for 1 h; filtration through silica with THF; column chromy. (silica gel, CH2Cl2/toluene);
DOI:10.1002/1521-3773(20020402)41:7<1183::AID-ANIE1183>3.0.CO;2-Z