Ethyl 2-bromo-3-(4-methoxyphenyl)-3-oxopropanoate

Base Information

Chemical Name:Ethyl 2-bromo-3-(4-methoxyphenyl)-3-oxopropanoate
CAS No.:87943-96-2
Molecular Formula:C12H13 Br O4
Molecular Weight:301.137
Hs Code.:2918990090
DSSTox Substance ID:DTXSID20516411
Mol file:87943-96-2.mol

Synonyms:87943-96-2;ethyl 2-bromo-3-(4-methoxyphenyl)-3-oxopropanoate;Ethyl 2-bromo-3-(4-methoxyphenyl)-3-oxo-propanoate;a-Bromo-4-methoxy-b-oxo-benzenepropanoic acid ethyl ester;SCHEMBL3129736;DTXSID20516411;OWFFTVVEZANQDO-UHFFFAOYSA-N;MFCD07783810;AKOS015961894;AC-15134;CS-0456846;ETHYL2-BROMO-3-(4-METHOXYPHENYL)-3-OXO-PROPANOATE

Suppliers and Price of Ethyl 2-bromo-3-(4-methoxyphenyl)-3-oxopropanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Ethyl2-bromo-3-(4-methoxyphenyl)-3-oxopropanoate 97%
5g
$ 1632.00

Crysdot
Ethyl2-bromo-3-(4-methoxyphenyl)-3-oxopropanoate 97%
1g
$ 465.00

American Custom Chemicals Corporation
ETHYL-2-BROMO-3-(4-METHOXYPHENYL)-3-OXO-PROPANOATE 95.00%
5MG
$ 495.08

Alichem
Ethyl2-bromo-3-(4-methoxyphenyl)-3-oxo-propanoate
5g
$ 1783.96

Alichem
Ethyl2-bromo-3-(4-methoxyphenyl)-3-oxo-propanoate
1g
$ 509.85

Total 7 raw suppliers

Chemical Property of Ethyl 2-bromo-3-(4-methoxyphenyl)-3-oxopropanoate

Chemical Property:

Vapor Pressure:2.44E-05mmHg at 25°C
Refractive Index:1.539
Boiling Point:359.1°C at 760 mmHg
PKA:7.58±0.27(Predicted)
Flash Point:171°C
PSA：52.60000
Density:1.423g/cm³
LogP:2.20450
XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:299.99972
Heavy Atom Count:17
Complexity:272

Purity/Quality:

98%+ ^*data from raw suppliers

Ethyl2-bromo-3-(4-methoxyphenyl)-3-oxopropanoate 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C(C(=O)C1=CC=C(C=C1)OC)Br

Technology Process of Ethyl 2-bromo-3-(4-methoxyphenyl)-3-oxopropanoate

There total 2 articles about Ethyl 2-bromo-3-(4-methoxyphenyl)-3-oxopropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 2881-83-6
ethyl 4-methoxybenzoylacetate

: 87943-96-2
ethyl 2-bromo-3-(4-methoxyphenyl)-3-oxopropanoate

Guidance literature:: With N-Bromosuccinimide; toluene-4-sulfonic acid; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1002/ejoc.201700868

Reference yield:

: 100-06-1
1-(4-methoxyphenyl)ethanone

: 87943-96-2
ethyl 2-bromo-3-(4-methoxyphenyl)-3-oxopropanoate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydride / benzene / Reflux

2: N-Bromosuccinimide / Milling

With N-Bromosuccinimide; sodium hydride; In benzene;
DOI:10.1016/j.bmcl.2015.02.004