(η5-C5H5)Re(NO)(PPh3)(COCH3)

Base Information

Chemical Name:(η5-C5H5)Re(NO)(PPh3)(COCH3)
CAS No.:82582-46-5
Molecular Formula:C₂₅H₂₃NO₂PRe
Molecular Weight:586.644
Hs Code.:

Synonyms:(η5-C5H5)Re(NO)(PPh3)(COCH3)

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Chemical Property of (η5-C5H5)Re(NO)(PPh3)(COCH3)

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Technology Process of (η5-C5H5)Re(NO)(PPh3)(COCH3)

There total 6 articles about (η5-C5H5)Re(NO)(PPh3)(COCH3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 82293-79-6
(η5-C5H5)Re(NO)(PPh3)(CO2CH3)

: 82582-46-5
(η5-C5H5)Re(NO)(PPh3)(COCH3)

Guidance literature:: With methylmagnesium bromide; In diethyl ether; toluene; MeMgBr in ether was added to a soln. of complex, a mixture was stirred for 0.5 h, inert atm.; evapn. in vac., extn. (acetone), filtration through the silica gel, evapn., washing with acetone, drying in vac.; elem. anal.;

Reference yield: 59.0%

: 99921-92-3
(C₅H₅)Re(NO)(P(C₆H₅)3)(C(O)CH₂Si(CH₃)3)

: 82582-46-5
(η5-C5H5)Re(NO)(PPh3)(COCH3)

: 99921-93-4
(C₅H₅)Re(NO)(P(C₆H₅)3)(C(CH₂)OSi(CH₃)3)

Guidance literature:: In melt; Re complex was put into glass tube, evacuated for 30 min and sealed, kept for 20 min at 160°C; cooled to room temp., transferred to glovebox, extd. (THF), evapd. in high vac.,extd. (ether), evapd. in high vac.; attempts to remove (C5H5)Re(NO)(PPh3)(COCH3) were unsuccessful;
DOI:10.1021/ja00266a012