(η5-C5H5)Re(NO)(PPh3)(CO2CH3)

Base Information

Chemical Name:(η5-C5H5)Re(NO)(PPh3)(CO2CH3)
CAS No.:82293-79-6
Molecular Formula:C₂₅H₂₃NO₃PRe
Molecular Weight:602.643
Hs Code.:

Synonyms:(η5-C5H5)Re(NO)(PPh3)(CO2CH3)

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Chemical Property of (η5-C5H5)Re(NO)(PPh3)(CO2CH3)

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Technology Process of (η5-C5H5)Re(NO)(PPh3)(CO2CH3)

There total 3 articles about (η5-C5H5)Re(NO)(PPh3)(CO2CH3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: [(μ5-C5H5)Re(NO)(CO)(P(C6H5)3)]BF4

: 124-41-4
sodium methylate

: 82293-79-6
(η5-C5H5)Re(NO)(PPh3)(CO2CH3)

Guidance literature:: With methanol; In dichloromethane; NaOMe in MeOH was added to a soln. of complex at -78°C, a mixture was stirred at -78°C for 20 min, warmed to room temp. and stirred for 0.5 h, inert atm.; evapn. in vac., extn. (toluene), filtration, evapn., drying in vac.;

Reference yield: 96.0%

: [(μ5-C5H5)Re(NO)(CO)(P(C6H5)3)]BF4

: 82293-79-6
(η5-C5H5)Re(NO)(PPh3)(CO2CH3)

Guidance literature:: With CH₃OH; Na; In methanol; To the slurry of complex in MeOH was added Na, the mixt. was stirred for 1 h (N2 atm.);; solvent was removed in vac., ppt. was dissolved in CH2Cl2, filtered, evapd. in vac., ppt. was washed with cold hexane and vac. dried;;

Reference yield: 57.0%

: 67-56-1
methanol

: (η5-cyclopentadienyl)rhenium(NO)(PPh3)(hydride)

: 124-38-9,18923-20-1
carbon dioxide

: 82293-79-6
(η5-C5H5)Re(NO)(PPh3)(CO2CH3)

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; n-BuLi soln. (hexane) addn. (-20°C), CO2 addn. (liquid N2), evapn. (room temp.), evapn., extg. (C6H6), filtering, evapn., THF and MeOH addn.; crystn. (-20°C, CH2Cl2 / pentane = 1 : 10);
DOI:10.1021/om980642j