1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate

Base Information

Chemical Name:1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate
CAS No.:1432519-06-6
Molecular Formula:C₃₂H₃₆O₄S₂Se
Molecular Weight:627.727
Hs Code.:

Synonyms:1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate

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Chemical Property of 1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate

Chemical Property:

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Technology Process of 1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate

There total 7 articles about 1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1432519-03-3
5-butyl-3-[1-hydroxy-4,4-bis(phenylsulfanyl)butyl]-3-(phenylselanyl)oxolan-2-one

: 75-36-5
acetyl chloride

: 1432519-06-6
1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate

Guidance literature:: With pyridine; dmap; In dichloromethane; at 0 ℃; for 3h; Cooling with ice;
DOI:10.1039/c3ob40115d

Reference yield:

: 371-42-6
4-Fluorothiophenol

: 1432519-06-6
1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate

Guidance literature:: Multi-step reaction with 5 steps

1.1: trifluoroacetic acid / dichloromethane / 24 h / 20 °C

2.1: tetra-(n-butyl)ammonium iodide / dimethyl sulfoxide / 24 h / 50 °C

3.1: diisobutylaluminium hydride / dichloromethane; toluene / 1.83 h / -78 - 0 °C / Cooling with ice

4.1: lithium diisopropyl amide / hexane; tetrahydrofuran / 0.75 h / -78 °C

4.2: 0.08 h

4.3: -78 °C

5.1: dmap; pyridine / dichloromethane / 3 h / 0 °C / Cooling with ice

With pyridine; dmap; tetra-(n-butyl)ammonium iodide; diisobutylaluminium hydride; trifluoroacetic acid; lithium diisopropyl amide; In tetrahydrofuran; hexane; dichloromethane; dimethyl sulfoxide; toluene;
DOI:10.1039/c3ob40115d

Reference yield:

: 1432519-38-4
1-({3-chloro-1-[(4-fluorophenyl)sulfanyl]propyl}sulfanyl)-4-fluorobenzene

: 1432519-06-6
1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate

Guidance literature:: Multi-step reaction with 4 steps

1.1: tetra-(n-butyl)ammonium iodide / dimethyl sulfoxide / 24 h / 50 °C

2.1: diisobutylaluminium hydride / dichloromethane; toluene / 1.83 h / -78 - 0 °C / Cooling with ice

3.1: lithium diisopropyl amide / hexane; tetrahydrofuran / 0.75 h / -78 °C

3.2: 0.08 h

3.3: -78 °C

4.1: dmap; pyridine / dichloromethane / 3 h / 0 °C / Cooling with ice

With pyridine; dmap; tetra-(n-butyl)ammonium iodide; diisobutylaluminium hydride; lithium diisopropyl amide; In tetrahydrofuran; hexane; dichloromethane; dimethyl sulfoxide; toluene;
DOI:10.1039/c3ob40115d