{Mn(CO)4(C₆H₅)2P(CH₂)3P(C₆H₅)2}⁽¹⁺⁾*BF₄^(1-)={Mn(CO)4((C₆H₅)2P(CH₂)3P(C₆H₅)2)}(BF₄)

Base Information

• Chemical Name: {Mn(CO)4(C₆H₅)2P(CH₂)3P(C₆H₅)2}⁽¹⁺⁾*BF₄^(1-)={Mn(CO)4((C₆H₅)2P(CH₂)3P(C₆H₅)2)}(BF₄)
• CAS No.: 145088-69-3
• Molecular Formula: BF₄*C₃₁H₂₆MnO₄P₂
• Molecular Weight: 666.235
• Mol file: 145088-69-3.mol

Synonyms:{Mn(CO)4(C₆H₅)2P(CH₂)3P(C₆H₅)2}⁽¹⁺⁾*BF₄^(1-)={Mn(CO)4((C₆H₅)2P(CH₂)3P(C₆H₅)2)}(BF₄)

Chemical Property of {Mn(CO)4(C₆H₅)2P(CH₂)3P(C₆H₅)2}⁽¹⁺⁾*BF₄^(1-)={Mn(CO)4((C₆H₅)2P(CH₂)3P(C₆H₅)2)}(BF₄)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Mn(CO)4(C₆H₅)2P(CH₂)3P(C₆H₅)2}⁽¹⁺⁾*BF₄^(1-)={Mn(CO)4((C₆H₅)2P(CH₂)3P(C₆H₅)2)}(BF₄)

There total 1 articles about {Mn(CO)4(C₆H₅)2P(CH₂)3P(C₆H₅)2}⁽¹⁺⁾*BF₄^(1-)={Mn(CO)4((C₆H₅)2P(CH₂)3P(C₆H₅)2)}(BF₄) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

silver tetrafluoroborate (14104-20-2) + fac-Mn(CO)3(1,3-bis(diphenylphosphino)propane)Br (78251-33-9) → {Mn(CO)4(C6H5)2P(CH2)3P(C6H5)2}(1+)*BF4(1-)={Mn(CO)4((C6H5)2P(CH2)3P(C6H5)2)}(BF4) (145088-69-3)

Guidance literature:

With CO; In dichloromethane; under Ar, addn. of a slight excess of AgBF4 to a refluxing soln. of Mn-complex while bubbling a stream of CO through the soln.; cooling after 16 h, filtration through Celite, concg., addn. of ether, vac.-drying, elem. anal.;

DOI:10.1016/S0277-5387(00)83162-9

Reference yield: 96.0%

{Mn(CO)4(C6H5)2P(CH2)3P(C6H5)2}(1+)*BF4(1-)={Mn(CO)4((C6H5)2P(CH2)3P(C6H5)2)}(BF4) (145088-69-3) → {(C6H5)2PCH2CH2CH2P(C6H5)2Mn(CO)3CHO}

Guidance literature:

With NaBH₄; In methanol; water; acetonitrile; byproducts: NaBF4, BH3; under argon, cooling a soln. of metal-complex (acetonitrile/methanol/water) to 0°C, addn. of slight excess of NaBH4 with stirring; filtn., drying (vac.);

DOI:10.1016/0022-328X(94)88015-8

Reference yield: 87.0%

propylamine (107-10-8,42939-71-9) + {Mn(CO)4(C6H5)2P(CH2)3P(C6H5)2}(1+)*BF4(1-)={Mn(CO)4((C6H5)2P(CH2)3P(C6H5)2)}(BF4) (145088-69-3) → {Mn(CO)3((C6H5)2P(CH2)3P(C6H5)2)(C(O)NHCH2CH2CH3)}

Guidance literature:

In further solvent(s); stirring (Ar, 1 day); evapn. in vac., recrstn. of solid (benzene/hexane), filtration of yellow crystals, washing (hexane), drying in vac., elem. anal.;

DOI:10.1016/S0277-5387(00)83162-9

upstream raw materials:

silver tetrafluoroborate

fac-Mn(CO)3(1,3-bis(diphenylphosphino)propane)Br