(1S)-N,N-Bis[2-(diphenylphosphanyl)ethyl]-1-phenylethan-1-amine

Base Information

Chemical Name:(1S)-N,N-Bis[2-(diphenylphosphanyl)ethyl]-1-phenylethan-1-amine
CAS No.:81510-19-2
Molecular Formula:C36H37 N P2
Molecular Weight:545.63
Hs Code.:
European Community (EC) Number:635-510-8
DSSTox Substance ID:DTXSID30508701
Wikidata:Q82365837
Mol file:81510-19-2.mol

Synonyms:81510-19-2;(1S)-N,N-Bis[2-(diphenylphosphanyl)ethyl]-1-phenylethan-1-amine;(1S)-N,N-bis(2-diphenylphosphanylethyl)-1-phenylethanamine;S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE;r(+)-n,n-bis(2-diphenylphosphinoethyl)-1-phenylethylamine;DTXSID30508701;(S)-(-)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine;(R)-2-(diphenylphosphino)-N-(2-(diphenylphosphino)ethyl)-N-(1-phenylethyl)ethanamine;(S)-(-)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine, >=98.0% (CHN)

Suppliers and Price of (1S)-N,N-Bis[2-(diphenylphosphanyl)ethyl]-1-phenylethan-1-amine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
(S)-(?)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine ≥98.0% (CHN)
500mg
$ 233.00

American Custom Chemicals Corporation
S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE 95.00%
5MG
$ 502.48

Total 1 raw suppliers

Chemical Property of (1S)-N,N-Bis[2-(diphenylphosphanyl)ethyl]-1-phenylethan-1-amine

Chemical Property:

Vapor Pressure:6.4E-16mmHg at 25°C
Boiling Point:632.8°C at 760 mmHg
Flash Point:336.5°C
PSA：30.42000
LogP:7.31540
XLogP3:7.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:12
Exact Mass:545.24012418
Heavy Atom Count:39
Complexity:558

Purity/Quality:

99% ^*data from raw suppliers

(S)-(?)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine ≥98.0% (CHN) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:C
Statements: 34
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C1=CC=CC=C1)N(CCP(C2=CC=CC=C2)C3=CC=CC=C3)CCP(C4=CC=CC=C4)C5=CC=CC=C5
Isomeric SMILES:C[C@@H](C1=CC=CC=C1)N(CCP(C2=CC=CC=C2)C3=CC=CC=C3)CCP(C4=CC=CC=C4)C5=CC=CC=C5

Technology Process of (1S)-N,N-Bis[2-(diphenylphosphanyl)ethyl]-1-phenylethan-1-amine

There total 1 articles about (1S)-N,N-Bis[2-(diphenylphosphanyl)ethyl]-1-phenylethan-1-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 2627-86-3
(-)-α-methylbenzylamine

: 2155-96-6
Diphenylvinylphosphine

: 81510-19-2
Bis-(2-diphenylphosphanyl-ethyl)-(1-phenyl-ethyl)-amine

Guidance literature:: n-butyllithium; In tetrahydrofuran; for 16h; Heating;
DOI:10.1016/S0040-4039(01)93014-X

Reference yield: 85.0%

: 12107-56-1
dichloro(cycloocta-1,5-diene)palladium (II)

: 81510-19-2
R-(+)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine

: 2923-28-6
silver trifluoromethanesulfonate

: [Pd(R-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine)(CF₃SO₃)](CF₃SO₃)*CH₃CN

Guidance literature:: In dichloromethane; Schlenk technique; addn. of a CH2Cl2 soln. of the R-(+)-amine to the Pd complex in Ch2Cl2, volatiles removed, residue redissolved in CH2Cl2, soln. of AgCF3SO3 in MeCN added, stirred at room temp. for 1 h, further addn. of AgCF3SO3, stirring for 1 h; soln. filtered, volume of filtrate was reduced, Et2O was added, ppt. wasrecrystd. from CH2Cl2/pentane, dried in vac.; elem. anal.;
DOI:10.1021/om010524n

Reference yield: 85.0%

: 14873-63-3
cis-bis(benzonitrile)dichloroplatinum(II)

: 81510-19-2
R-(+)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine

: cis-[PtCl₂((R)-N,N-bis(2-diphenylphosphinoethyl)-1-phenyl-ethylamine)]

Guidance literature:: In benzene; under Ar; mixt. was refluxed for 2 h; mixt. was cooled to room temp., solid was filtered off, washed with coldbenzene; elem. anal.;
DOI:10.1016/S0020-1693(01)00384-X