Fe(α-benzyldioxime)2(CH3S)2(glyoxime)(BF)2

Base Information

• Chemical Name: Fe(α-benzyldioxime)2(CH3S)2(glyoxime)(BF)2
• CAS No.: 439120-07-7
• Molecular Formula: C₃₂H₂₆B₂F₂FeN₆O₆S₂
• Molecular Weight: 770.193
• Mol file: 439120-07-7.mol

Synonyms:Fe(α-benzyldioxime)2(CH3S)2(glyoxime)(BF)2

Chemical Property of Fe(α-benzyldioxime)2(CH3S)2(glyoxime)(BF)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Fe(α-benzyldioxime)2(CH3S)2(glyoxime)(BF)2

There total 2 articles about Fe(α-benzyldioxime)2(CH3S)2(glyoxime)(BF)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

FeBd2(Cl2Gm)(BF)2 (380456-14-4) + methylthiol (74-93-1) → Fe(α-benzyldioxime)2(CH3S)2(glyoxime)(BF)2 (439120-07-7)

Guidance literature:

With (C₂H₅)3N; In dichloromethane; iron complex, methanethiol and Et3N were dissolved/suspended in CH2Cl2, left overnight; washed with 3% aq. HCl, dried over CaCl2, filtered, concd. in vac., prcipitated with hexane, washed with MeOH, hexane, dried in vac.;

DOI:10.1016/j.ica.2008.03.055

Reference yield: 76.0%

FeBd2(Cl2Gm)(BF)2 (380456-14-4) + methylthiol (74-93-1) + potassium 2,2-dimethyl-1-propanolate (55553-85-0) → Fe(α-benzyldioxime)2(CH3S)2(glyoxime)(BF)2 (439120-07-7)

Guidance literature:

With MeI; K₂CO₃; CH₃COOH; In tetrahydrofuran; solns. of K-contg. compd. and MeSH in THF were added to THF under Ar; the react. mixt. was cooled to -20°C; Fe-contg. compd. (1 mmol) wasadded to the soln.; the mixt. was stirred for 2 h at room temp. and ref luxed for 2 h; the solvent was distd. off, the mixt. was cooled to room temp. and MeI and K2CO3 were added; stirring for 2 h; the mixt. was dild. with EtOH; CH3COOH was added and the react. mixt. was heated to b.p.; the solid was pptd. with H2O; elem. anal.;

DOI:10.1039/b107021p

Reference yield: 20.0%

tetrabutylammonium tetrachloroplatinate + Fe(α-benzyldioxime)2(CH3S)2(glyoxime)(BF)2 (439120-07-7) → 2(C4H9)4N(1+)*(Fe(C6H5CNONOCC6H5)2(ONCSCSNO)(BF)2)2Pt(2-)=C92H112N14O12S4B4F4Fe2Pt + ((n-C4H9)4N)2[((Fe(α-benzyldioxime)2(S2(glyoxime)(BF)2)2Pt2Cl2]

Guidance literature:

In nitromethane; iron and platinum complexes were refluxed in CH3NO2 for 6 h with stirring, cooled to room temp.; filtered, concd. in vac., pptd. with Et2O, washed with MeOH, Et2O, hexane, dried in vac., elem. anal.;

DOI:10.1016/j.ica.2008.03.055

upstream raw materials:

FeBd2(Cl2Gm)(BF)2

methylthiol

potassium 2,2-dimethyl-1-propanolate