Tris(1-methylimidazol-2-yl)phosphine

Base Information

Chemical Name:Tris(1-methylimidazol-2-yl)phosphine
CAS No.:80679-27-2
Molecular Formula:C₁₂H₁₅N₆P
Molecular Weight:274.265
Hs Code.:
DSSTox Substance ID:DTXSID70513359
Nikkaji Number:J2.563.036J
Wikidata:Q82373135
Mol file:80679-27-2.mol

Synonyms:80679-27-2;tris(1-methylimidazol-2-yl)phosphine;tris(1-methylimidazol-2-yl)phosphane;1H-Imidazole,2,2',2''-phosphinidynetris[1-methyl-;SCHEMBL3192088;DTXSID70513359;2-[BIS(1-METHYL-1H-IMIDAZOL-2-YL)PHOSPHINO]-1-METHYL-1H-IMIDAZOLE;AKOS000122718;SR-05000015322;SR-05000015322-1;2,2',2''-Phosphanetriyltris(1-methyl-1H-imidazole)

Suppliers and Price of Tris(1-methylimidazol-2-yl)phosphine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
2-[BIS(1-METHYL-1H-IMIDAZOL-2-YL)PHOSPHINO]-1-METHYL-1H-IMIDAZOLE 95.00%
5MG
$ 503.28

Total 3 raw suppliers

Chemical Property of Tris(1-methylimidazol-2-yl)phosphine

Chemical Property:

PSA：67.05000
LogP:-0.35470
XLogP3:-0.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:274.10958150
Heavy Atom Count:19
Complexity:269

Purity/Quality:: 2-[BIS(1-METHYL-1H-IMIDAZOL-2-YL)PHOSPHINO]-1-METHYL-1H-IMIDAZOLE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CN1C=CN=C1P(C2=NC=CN2C)C3=NC=CN3C

Technology Process of Tris(1-methylimidazol-2-yl)phosphine

There total 2 articles about Tris(1-methylimidazol-2-yl)phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 616-47-7
1-methyl-1H-imidazole

: 80679-27-2
tris(1-methylimidazol-2-yl)phosphine

Guidance literature:: 1-methyl-1H-imidazole; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere;

With phosphorus trichloride; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

Reference yield: 66.0%

: 35342-89-3
1-methyl-2-(trimethylsilyl)-1H-imidazole

: 80679-27-2
tris(1-methylimidazol-2-yl)phosphine

Guidance literature:: With phosphorus trichloride; 1.) 0-5 deg C, 2 h, 2.) 90-95 deg C, 18 h;
DOI:10.1021/jo00347a023

Reference yield: 29.0%

: pentafluorophenyl(tetrahydrothiophene)gold(I)

: 80679-27-2
tris(1-methylimidazol-2-yl)phosphine

: 1009735-47-0
bis(pentafluorophenyl)-μ-[tris(1-methylimidazol-2-yl)phosphine-κ2-P,N]digold(I)

Guidance literature:: In tetrahydrofuran; a suspn. of complex and phosphine in THF was stirred for 30 min; volatiles were removed in vac., the solid was extd. with THF, filtered, dissolved in CH2Cl2, filtered, recrystd. from acetone layered with pentane, dried in vac.; elem. anal.;
DOI:10.1039/b709896k