(Z)-2-(2-methyl-3-phenyl-1-propenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:(Z)-2-(2-methyl-3-phenyl-1-propenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:1187524-95-3
Molecular Formula:C₁₆H₂₃BO₂
Molecular Weight:258.168
Hs Code.:

Synonyms:(Z)-2-(2-methyl-3-phenyl-1-propenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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Chemical Property of (Z)-2-(2-methyl-3-phenyl-1-propenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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Technology Process of (Z)-2-(2-methyl-3-phenyl-1-propenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 1 articles about (Z)-2-(2-methyl-3-phenyl-1-propenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1187524-86-2
(Z)-2-(2-bromoprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 100-39-0
benzyl bromide

: 1187524-95-3
(Z)-2-(2-methyl-3-phenyl-1-propenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: benzyl bromide; With zinc; In tetrahydrofuran; Inert atmosphere;

(Z)-2-(2-bromoprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; With bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; at 0 - 23 ℃; Inert atmosphere;
DOI:10.1021/ol901566e

Reference yield: 62.0%

: 1187524-95-3
(Z)-2-(2-methyl-3-phenyl-1-propenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1338073-31-6
3-phenylpropyl 2,4,6-triisopropylbenzoate

: (S,Z)-4,4,5,5-tetramethyl-2-(5-methyl-1,6-diphenylhex-4-en-3-yl)-1,3,2-dioxaborolane

Guidance literature:: 3-phenylpropyl 2,4,6-triisopropylbenzoate; With sec.-butyllithium; sparteine; In diethyl ether; hexane; cyclohexane; at -78 ℃; for 4h; Inert atmosphere;

(Z)-2-(2-methyl-3-phenyl-1-propenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; In diethyl ether; hexane; cyclohexane; at -78 ℃; for 1h; Inert atmosphere;

In hexane; chloroform; cyclohexane; at 45 ℃; for 16h; Inert atmosphere;
DOI:10.1002/anie.201407127

Reference yield:

: 1187524-95-3
(Z)-2-(2-methyl-3-phenyl-1-propenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1338073-31-6
3-phenylpropyl 2,4,6-triisopropylbenzoate

: (Z)-4,4,5,5-tetramethyl-2-(5-methyl-1,6-diphenylhex-4-en-3-yl)-1,3,2-dioxaborolane

Guidance literature:: 3-phenylpropyl 2,4,6-triisopropylbenzoate; With N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium; In diethyl ether; hexane; cyclohexane; at -78 ℃; for 4h; Inert atmosphere;

(Z)-2-(2-methyl-3-phenyl-1-propenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; In diethyl ether; hexane; cyclohexane; at -78 ℃; for 1h; Inert atmosphere;

In hexane; chloroform; cyclohexane; at 45 ℃; for 16h; Inert atmosphere;
DOI:10.1002/anie.201407127