1,5-anhydro-2-deoxy-1,2-C-[exo-(N-methyl-N-methoxy)amidocarboxymethylene]-3,4,6-tri-O-benzyl-α-D-glucitol

Base Information

Chemical Name:1,5-anhydro-2-deoxy-1,2-C-[exo-(N-methyl-N-methoxy)amidocarboxymethylene]-3,4,6-tri-O-benzyl-α-D-glucitol
CAS No.:1361033-41-1
Molecular Formula:C₃₁H₃₅NO₆
Molecular Weight:517.622
Hs Code.:

Synonyms:1,5-anhydro-2-deoxy-1,2-C-[exo-(N-methyl-N-methoxy)amidocarboxymethylene]-3,4,6-tri-O-benzyl-α-D-glucitol

Suppliers and Price of 1,5-anhydro-2-deoxy-1,2-C-[exo-(N-methyl-N-methoxy)amidocarboxymethylene]-3,4,6-tri-O-benzyl-α-D-glucitol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,5-anhydro-2-deoxy-1,2-C-[exo-(N-methyl-N-methoxy)amidocarboxymethylene]-3,4,6-tri-O-benzyl-α-D-glucitol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,5-anhydro-2-deoxy-1,2-C-[exo-(N-methyl-N-methoxy)amidocarboxymethylene]-3,4,6-tri-O-benzyl-α-D-glucitol

There total 3 articles about 1,5-anhydro-2-deoxy-1,2-C-[exo-(N-methyl-N-methoxy)amidocarboxymethylene]-3,4,6-tri-O-benzyl-α-D-glucitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 935398-00-8
1,5-anhydro-2-deoxy-1,2-C-(exo-carboxymethylene)-3,4,6-tri-O-benzyl-α-D-glucitol

: 6638-79-5
N,O-dimethylhydroxylamine*hydrochloride

: 1361033-41-1
1,5-anhydro-2-deoxy-1,2-C-[exo-(N-methyl-N-methoxy)amidocarboxymethylene]-3,4,6-tri-O-benzyl-α-D-glucitol

Guidance literature:: 1,5-anhydro-2-deoxy-1,2-C-(exo-carboxymethylene)-3,4,6-tri-O-benzyl-α-D-glucitol; With 4-methyl-morpholine; 2-chloro-4,6-dimethoxy-1 ,3,5-triazine; In tetrahydrofuran; at 20 ℃; for 1h;

N,O-dimethylhydroxylamine*hydrochloride; In tetrahydrofuran;
DOI:10.1016/j.carres.2012.01.006

Reference yield:

: 55628-54-1
3,4,6-tri-O-benzyl-D-glucal

: 1361033-41-1
1,5-anhydro-2-deoxy-1,2-C-[exo-(N-methyl-N-methoxy)amidocarboxymethylene]-3,4,6-tri-O-benzyl-α-D-glucitol

Guidance literature:: Multi-step reaction with 3 steps

1.1: rhodium-catalyst

2.1: water; potassium hydroxide / ethanol / 1 h / Reflux

2.2: 0 °C

3.1: 4-methyl-morpholine; 2-chloro-4,6-dimethoxy-1 ,3,5-triazine / tetrahydrofuran / 1 h / 20 °C

With 4-methyl-morpholine; 2-chloro-4,6-dimethoxy-1 ,3,5-triazine; water; potassium hydroxide; In tetrahydrofuran; ethanol;
DOI:10.1016/j.carres.2012.01.006

Reference yield:

: ethyl (1S,3R,4S,5R,6S,7S)-4,5-bis(benzyloxy)-3-(benzyloxymethyl)-2-oxabicyclo[4.1.0]heptane-7-carboxylate

: 1361033-41-1
1,5-anhydro-2-deoxy-1,2-C-[exo-(N-methyl-N-methoxy)amidocarboxymethylene]-3,4,6-tri-O-benzyl-α-D-glucitol

Guidance literature:: Multi-step reaction with 2 steps

1.1: water; potassium hydroxide / ethanol / 1 h / Reflux

1.2: 0 °C

2.1: 4-methyl-morpholine; 2-chloro-4,6-dimethoxy-1 ,3,5-triazine / tetrahydrofuran / 1 h / 20 °C

With 4-methyl-morpholine; 2-chloro-4,6-dimethoxy-1 ,3,5-triazine; water; potassium hydroxide; In tetrahydrofuran; ethanol;
DOI:10.1016/j.carres.2012.01.006