methyl 2-((((((perfluorobenzoyl)oxy)imino)(phenyl)methyl)thio)methyl)acrylate

Base Information

Chemical Name:methyl 2-((((((perfluorobenzoyl)oxy)imino)(phenyl)methyl)thio)methyl)acrylate
CAS No.:1568950-46-8
Molecular Formula:C₁₉H₁₂F₅NO₄S
Molecular Weight:445.367
Hs Code.:

Synonyms:methyl 2-((((((perfluorobenzoyl)oxy)imino)(phenyl)methyl)thio)methyl)acrylate

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Chemical Property of methyl 2-((((((perfluorobenzoyl)oxy)imino)(phenyl)methyl)thio)methyl)acrylate

Chemical Property:

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Technology Process of methyl 2-((((((perfluorobenzoyl)oxy)imino)(phenyl)methyl)thio)methyl)acrylate

There total 4 articles about methyl 2-((((((perfluorobenzoyl)oxy)imino)(phenyl)methyl)thio)methyl)acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 4224-69-5
methyl 2-(bromomethyl)propenoate

pentafluorobenzoylchloride: 2251-50-5
pentafluorobenzoylchloride

: 15177-34-1
thiobenzhydroxamic acid

: 1568950-46-8
methyl 2-((((((perfluorobenzoyl)oxy)imino)(phenyl)methyl)thio)methyl)acrylate

Guidance literature:: methyl 2-(bromomethyl)propenoate; thiobenzhydroxamic acid; With tetra-(n-butyl)ammonium iodide; triethylamine; In diethyl ether; at 20 ℃;

pentafluorobenzoylchloride; With triethylamine; In diethyl ether; at 20 ℃; for 0.5h;
DOI:10.1021/jo500080x

Reference yield:

: 100-52-7
benzaldehyde

: 1568950-46-8
methyl 2-((((((perfluorobenzoyl)oxy)imino)(phenyl)methyl)thio)methyl)acrylate

Guidance literature:: Multi-step reaction with 4 steps

1.1: hydroxylamine hydrochloride; sodium hydroxide / N,N-dimethyl-formamide; water / 1 h / 30 °C

2.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.5 h / 20 °C

3.1: sodium sulfide; triethylamine / diethyl ether; water / 1 h / 20 °C

4.1: triethylamine; tetra-(n-butyl)ammonium iodide / diethyl ether / 20 °C

4.2: 0.5 h / 20 °C

With sodium sulfide; N-chloro-succinimide; hydroxylamine hydrochloride; tetra-(n-butyl)ammonium iodide; triethylamine; sodium hydroxide; In diethyl ether; water; N,N-dimethyl-formamide;
DOI:10.1021/jo500080x

Reference yield:

: 932-90-1
Benzaldoxime

: 1568950-46-8
methyl 2-((((((perfluorobenzoyl)oxy)imino)(phenyl)methyl)thio)methyl)acrylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.5 h / 20 °C

2.1: sodium sulfide; triethylamine / diethyl ether; water / 1 h / 20 °C

3.1: triethylamine; tetra-(n-butyl)ammonium iodide / diethyl ether / 20 °C

3.2: 0.5 h / 20 °C

With sodium sulfide; N-chloro-succinimide; tetra-(n-butyl)ammonium iodide; triethylamine; In diethyl ether; water; N,N-dimethyl-formamide;
DOI:10.1021/jo500080x