1-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-propan-2-one

Base Information

• Chemical Name: 1-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-propan-2-one
• CAS No.: 1628708-15-5
• Molecular Formula: C₂₅H₃₈O₃Si₂
• Molecular Weight: 442.746

Synonyms:1-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-propan-2-one

Chemical Property of 1-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-propan-2-one

Chemical Property:

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Technology Process of 1-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-propan-2-one

There total 4 articles about 1-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-propan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tert-butyldimethylsilyl chloride (18162-48-6) + 1-O-(tert-butyldiphenylsilyl)-1,3-dihydroxy-2-propanone (172843-09-3) → 1-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-propan-2-one (1628708-15-5)

Guidance literature:

With 1H-imidazole; In dichloromethane; at 0 ℃; for 2h;

DOI:10.1016/j.bmc.2014.04.024

Reference yield:

2-(tert-butyl-dimethyl-silanyloxymethyl)-acrylic acid methyl ester (144828-45-5) → 1-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-propan-2-one (1628708-15-5)

Guidance literature:

Multi-step reaction with 2 steps

1: diisobutylaluminium hydride

2: ozone

With diisobutylaluminium hydride; ozone;

DOI:10.1021/acs.orglett.6b00783

Reference yield:

C26H40O2Si2 → 1-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-propan-2-one (1628708-15-5)

Guidance literature:

With ozone;

DOI:10.1021/acs.orglett.6b00783

upstream raw materials:

tert-butyldimethylsilyl chloride

1-O-(tert-butyldiphenylsilyl)-1,3-dihydroxy-2-propanone

tert-butylchlorodiphenylsilane

2-(tert-butyl-dimethyl-silanyloxymethyl)-acrylic acid methyl ester

Downstream raw materials:

C₄₀H₄₉NO₅Si

5-((tert-butyldimethylsilyloxy)methyl)-5-((tert-butyldiphenylsilyloxy)methyl)dihydrofuran-2(3H)-one

(E)-5-((tert-butyldimethylsilyloxy)methyl)-5-((tert-butyldiphenylsilyloxy)methyl)-3-((1-methyl-1H-indol-4-yl)methylene)dihydrofuran-2(3H)-one

(E)-5-((tert-butyldimethylsilyloxy)methyl)-5-((tert-butyldiphenylsilyloxy)methyl)-3-((1-methyl-1H-indol-5-yl)methylene)dihydrofuran-2(3H)-one

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