ba-D-galacto-Hexodialdo-1,5-pyranoside, methyl, 6-hydrate (9CI)

Base Information

• Chemical Name: ba-D-galacto-Hexodialdo-1,5-pyranoside, methyl, 6-hydrate (9CI)
• CAS No.: 752993-28-5
• Molecular Formula: C₇H₁₄O₇
• Molecular Weight: 210.184
• Mol file: 752993-28-5.mol

Synonyms:bta-D-galacto-Hexodialdo-1,5-pyranoside,methyl,6-hydrate(9CI);ba-D-galacto-Hexodialdo-1,5-pyranoside, methyl, 6-hydrate (9CI)

Chemical Property of ba-D-galacto-Hexodialdo-1,5-pyranoside, methyl, 6-hydrate (9CI)

Chemical Property:

• PSA: 119.61000
• LogP: -3.24890

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ba-D-galacto-Hexodialdo-1,5-pyranoside, methyl, 6-hydrate (9CI)

There total 1 articles about ba-D-galacto-Hexodialdo-1,5-pyranoside, methyl, 6-hydrate (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl beta-D-galactopyranoside (1824-94-8) → (2S,3R,4S,5R,6R)-2-Dihydroxymethyl-6-methoxy-tetrahydro-pyran-3,4,5-triol (752993-28-5)

Guidance literature:

With D-galactose oxidase; oxygen; catalase; In water; pH=7;

DOI:10.1016/S0040-4039(02)00479-3

Reference yield:

(2S,3R,4S,5R,6R)-2-Dihydroxymethyl-6-methoxy-tetrahydro-pyran-3,4,5-triol (752993-28-5) → 4-deoxy-β-D-xylo-hexopyranose (23397-23-1)

Guidance literature:

Multi-step reaction with 4 steps

1: L-proline / 5 h / 70 °C

2: hydrogen; palladium 10% on activated carbon / 2 h / 20 °C / 760.05 Torr

3: sodium tetrahydroborate / 0.5 h / 0 °C

4: hydrogenchloride / water / 24 h / 70 °C / pH 1.5

With hydrogenchloride; sodium tetrahydroborate; palladium 10% on activated carbon; hydrogen; L-proline; In water;

DOI:10.1021/acscatal.1c04679

Reference yield:

(2S,3R,4S,5R,6R)-2-Dihydroxymethyl-6-methoxy-tetrahydro-pyran-3,4,5-triol (752993-28-5) → methyl 4-deoxy-β-D-xylo-hexopyranoside (51385-57-0)

Guidance literature:

Multi-step reaction with 3 steps

1: L-proline / 5 h / 70 °C

2: hydrogen; palladium 10% on activated carbon / 2 h / 20 °C / 760.05 Torr

3: sodium tetrahydroborate / 0.5 h / 0 °C

With sodium tetrahydroborate; palladium 10% on activated carbon; hydrogen; L-proline;

DOI:10.1021/acscatal.1c04679

upstream raw materials:

methyl beta-D-galactopyranoside

Downstream raw materials:

methyl 4-deoxy-β-D-xylo-hexopyranoside

4-deoxy-β-D-xylo-hexopyranose