3-(tert-butyl-diphenyl-silanyloxy)-7,8-dihydroxy-5-(4-methoxy-benzyloxy)-octanethioic acid S-tert-butyl ester

Base Information

Chemical Name:3-(tert-butyl-diphenyl-silanyloxy)-7,8-dihydroxy-5-(4-methoxy-benzyloxy)-octanethioic acid S-tert-butyl ester
CAS No.:910046-77-4
Molecular Formula:C₃₆H₅₀O₆SSi
Molecular Weight:638.941
Hs Code.:

3-(<i>tert</i>-butyl-diphenyl-silanyloxy)-7,8-dihydroxy-5-(4-methoxy-benzyloxy)-octanethioic acid <i>S</i>-<i>tert</i>-butyl ester

Synonyms:3-(tert-butyl-diphenyl-silanyloxy)-7,8-dihydroxy-5-(4-methoxy-benzyloxy)-octanethioic acid S-tert-butyl ester

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Chemical Property of 3-(tert-butyl-diphenyl-silanyloxy)-7,8-dihydroxy-5-(4-methoxy-benzyloxy)-octanethioic acid S-tert-butyl ester

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Technology Process of 3-(tert-butyl-diphenyl-silanyloxy)-7,8-dihydroxy-5-(4-methoxy-benzyloxy)-octanethioic acid S-tert-butyl ester

There total 7 articles about 3-(tert-butyl-diphenyl-silanyloxy)-7,8-dihydroxy-5-(4-methoxy-benzyloxy)-octanethioic acid S-tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 910046-76-3
(3R,5S)-3-(tert-butyldiphenylsilanyloxy)-5-(4-methoxybenzyloxy)oct-7-enethioic acid S-tert-butyl ester

: 910046-77-4
3-(tert-butyl-diphenyl-silanyloxy)-7,8-dihydroxy-5-(4-methoxy-benzyloxy)-octanethioic acid S-tert-butyl ester

Guidance literature:: With osmium(VIII) oxide; water; 4-methylmorpholine N-oxide; In tetrahydrofuran; tert-butyl alcohol; at 20 ℃; for 14h;
DOI:10.1021/ol061173h

Reference yield:

: 910046-60-5
(3R,5S)-3-hydroxy-5-(4-methoxybenzyloxy)oct-7-enethioic acid S-tert-butyl ester

: 910046-77-4
3-(tert-butyl-diphenyl-silanyloxy)-7,8-dihydroxy-5-(4-methoxy-benzyloxy)-octanethioic acid S-tert-butyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / imidazole / dimethylformamide / 24 h / 20 °C

2: 4-methylmorpholine-N-oxide; OsO₄ / 2-methyl-propan-2-ol; tetrahydrofuran; H₂O / 14 h / 20 °C

With 1H-imidazole; osmium(VIII) oxide; 4-methylmorpholine N-oxide; In tetrahydrofuran; water; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1016/j.tetlet.2006.09.094

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 910046-77-4
3-(tert-butyl-diphenyl-silanyloxy)-7,8-dihydroxy-5-(4-methoxy-benzyloxy)-octanethioic acid S-tert-butyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: imidazole / dimethylformamide / 24 h / 20 °C

2: OsO₄; H₂O; 4-methylmorpholine N-oxide / tetrahydrofuran; 2-methyl-propan-2-ol / 14 h / 20 °C

With 1H-imidazole; osmium(VIII) oxide; water; 4-methylmorpholine N-oxide; In tetrahydrofuran; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1021/ol061173h