C₅₀H₉₀NO₁₃PSi₂

Base Information

Chemical Name:C₅₀H₉₀NO₁₃PSi₂
CAS No.:724765-14-4
Molecular Formula:C₅₀H₉₀NO₁₃PSi₂
Molecular Weight:1000.41
Hs Code.:

C<sub>50</sub>H<sub>90</sub>NO<sub>13</sub>PSi<sub>2</sub>

Synonyms:C₅₀H₉₀NO₁₃PSi₂

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₅₀H₉₀NO₁₃PSi₂

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Technology Process of C₅₀H₉₀NO₁₃PSi₂

There total 32 articles about C₅₀H₉₀NO₁₃PSi₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 67-56-1
methanol

: 724765-28-0
[2-[5-[6-(1-benzyloxymethyl-propyl)-4-cyano-2,2-dimethyl-[1,3]dioxan-4-yl]-2-(tert-butyl-dimethyl-silanyloxy)-pentyl]-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-oxo-hexahydro-pyrano[4,3-b]pyran-7-ylmethyl]-phosphonic acid diethyl ester

: 724765-14-4
C₅₀H₉₀NO₁₃PSi₂

Guidance literature:: With n-butyllithium; lithium methanolate; at 23 ℃; for 1h;
DOI:10.1002/anie.200453697

Reference yield:

: 127793-67-3
(S)‐7‐(benzyloxy)hept‐1‐en‐4‐ol

: 724765-14-4
C₅₀H₉₀NO₁₃PSi₂

Guidance literature:: Multi-step reaction with 18 steps

1.1: O₃ / CH₂Cl₂; methanol / -78 °C

1.2: 97 percent / NaBH₄ / CH₂Cl₂; methanol / 1.5 h / -78 - 23 °C

2.1: TEMPO; aq. KBr; NaOCl / NaHCO₃ / CH₂Cl₂ / 0.33 h / 0 °C

3.1: 18-crown-6; TMSCN / CH₂Cl₂ / 1 h / 23 °C

3.2: 1.14 g / pyridinium p-toluenesulfonate / CH₂Cl₂; methanol / 5 h / 23 °C

4.1: 88 percent / pyridinium p-toluenesulfonate / acetone / 19 h / 68 °C

5.1: 92 percent / LDA; N,N'-dimethyl-N,N'-propyleneurea / tetrahydrofuran; hexane / 0.5 h / -40 °C

6.1: Dowex 50X₂-100 ion-exchange resin; H₂O / methanol / 12 h / 23 °C

7.1: 0.74 g / Et₃N / methanol / 23 °C

8.1: 89 percent / pyridinium p-toluenesulfonate / methanol / 24 h / 23 °C

9.1: 97 percent / imidazole; DMAP / dimethylformamide / 13 h / 23 °C

10.1: 93 percent / Li; NH₃ / tetrahydrofuran / 0.2 h / -78 °C

11.1: 92 percent / I₂; PPh₃; imidazole / benzene / 0.17 h / 23 °C

12.1: 93 percent / LDA; N,N'-dimethyl-N,N'-propyleneurea / tetrahydrofuran; hexane / 0.25 h / -40 °C

13.1: 91 percent / NMO; OsO₄ / 2-methyl-propan-2-ol; H₂O / 12.75 h / 23 °C

14.1: 94 percent / Pb(OAc)4; Na₂CO₃ / CH₂Cl₂ / 0.75 h / -10 - 23 °C

15.1: 90 percent / n-BuLi; DMPU / tetrahydrofuran / 0.25 h / -78 °C

16.1: 87 percent / 4-methylmorpholine; 4 Angstroem molecular sieves; NMO / TPAP / acetonitrile / 1.67 h / 23 °C

17.1: 98 percent / MeOLi; n-BuLi / 1 h / 23 °C

With 4-methyl-morpholine; 1H-imidazole; lead(IV) acetate; dmap; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; osmium(VIII) oxide; n-butyllithium; N-methyl-2-indolinone; 18-crown-6 ether; trimethylsilyl cyanide; 4 A molecular sieve; Dowex 50X₂-100 ion-exchange resin; lithium methanolate; ammonia; water; iodine; pyridinium p-toluenesulfonate; lithium; sodium carbonate; ozone; triethylamine; triphenylphosphine; potassium bromide; lithium diisopropyl amide; tetrapropylammonium perruthennate; sodium hydrogencarbonate; In tetrahydrofuran; methanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; acetone; acetonitrile; tert-butyl alcohol; benzene;
DOI:10.1002/anie.200453697

Reference yield:

: 83458-93-9
(3S)-6-(Benzyloxy)hexane-1,3-diol

: 724765-14-4
C₅₀H₉₀NO₁₃PSi₂

Guidance literature:: Multi-step reaction with 17 steps

1.1: TEMPO; aq. KBr; NaOCl / NaHCO₃ / CH₂Cl₂ / 0.33 h / 0 °C

2.1: 18-crown-6; TMSCN / CH₂Cl₂ / 1 h / 23 °C

2.2: 1.14 g / pyridinium p-toluenesulfonate / CH₂Cl₂; methanol / 5 h / 23 °C

3.1: 88 percent / pyridinium p-toluenesulfonate / acetone / 19 h / 68 °C

4.1: 92 percent / LDA; N,N'-dimethyl-N,N'-propyleneurea / tetrahydrofuran; hexane / 0.5 h / -40 °C

5.1: Dowex 50X₂-100 ion-exchange resin; H₂O / methanol / 12 h / 23 °C

6.1: 0.74 g / Et₃N / methanol / 23 °C

7.1: 89 percent / pyridinium p-toluenesulfonate / methanol / 24 h / 23 °C

8.1: 97 percent / imidazole; DMAP / dimethylformamide / 13 h / 23 °C

9.1: 93 percent / Li; NH₃ / tetrahydrofuran / 0.2 h / -78 °C

10.1: 92 percent / I₂; PPh₃; imidazole / benzene / 0.17 h / 23 °C

11.1: 93 percent / LDA; N,N'-dimethyl-N,N'-propyleneurea / tetrahydrofuran; hexane / 0.25 h / -40 °C

12.1: 91 percent / NMO; OsO₄ / 2-methyl-propan-2-ol; H₂O / 12.75 h / 23 °C

13.1: 94 percent / Pb(OAc)4; Na₂CO₃ / CH₂Cl₂ / 0.75 h / -10 - 23 °C

14.1: 90 percent / n-BuLi; DMPU / tetrahydrofuran / 0.25 h / -78 °C

15.1: 87 percent / 4-methylmorpholine; 4 Angstroem molecular sieves; NMO / TPAP / acetonitrile / 1.67 h / 23 °C

16.1: 98 percent / MeOLi; n-BuLi / 1 h / 23 °C

With 4-methyl-morpholine; 1H-imidazole; lead(IV) acetate; dmap; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; osmium(VIII) oxide; n-butyllithium; N-methyl-2-indolinone; 18-crown-6 ether; trimethylsilyl cyanide; 4 A molecular sieve; Dowex 50X₂-100 ion-exchange resin; lithium methanolate; ammonia; water; iodine; pyridinium p-toluenesulfonate; lithium; sodium carbonate; triethylamine; triphenylphosphine; potassium bromide; lithium diisopropyl amide; tetrapropylammonium perruthennate; sodium hydrogencarbonate; In tetrahydrofuran; methanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; acetone; acetonitrile; tert-butyl alcohol; benzene;
DOI:10.1002/anie.200453697