1-methoxy-4-[[(1S,2R,3R,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]-1-cyclohexyl]oxymethyl]benzene

Base Information

Chemical Name:1-methoxy-4-[[(1S,2R,3R,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]-1-cyclohexyl]oxymethyl]benzene
CAS No.:214203-48-2
Molecular Formula:C₅₀H₅₂O₇
Molecular Weight:764.959
Hs Code.:

Synonyms:1-methoxy-4-[[(1S,2R,3R,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]-1-cyclohexyl]oxymethyl]benzene

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Chemical Property of 1-methoxy-4-[[(1S,2R,3R,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]-1-cyclohexyl]oxymethyl]benzene

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Technology Process of 1-methoxy-4-[[(1S,2R,3R,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]-1-cyclohexyl]oxymethyl]benzene

There total 7 articles about 1-methoxy-4-[[(1S,2R,3R,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]-1-cyclohexyl]oxymethyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 100-39-0
benzyl bromide

: 214203-47-1
(1R,2S,3R,4R,5S,6R)-2,3,4-tris(benzyloxy)-6-(hydroxymethyl)-5-[(4-methoxybenzyl)oxy]cyclohexanol

: 214203-48-2
1-methoxy-4-[[(1S,2R,3R,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]-1-cyclohexyl]oxymethyl]benzene

Guidance literature:: With sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide; for 96h; Ambient temperature;
DOI:10.1016/S0040-4039(98)01458-0

Reference yield:

: 85798-11-4
(4S,5R,6S)-4,5,6-tris-benzyloxycyclohex-2-en-1-one

: 214203-48-2
1-methoxy-4-[[(1S,2R,3R,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]-1-cyclohexyl]oxymethyl]benzene

Guidance literature:: Multi-step reaction with 5 steps

1.1: 87 percent / CeCl₃*7H₂O; NaBH₄ / methanol / 0.25 h / 0 °C

2.1: 100 percent / mCPBA; Na₂HPO₄ / CH₂Cl₂ / 96 h / 20 °C

3.1: 93 percent / NaH / dimethylformamide; tetrahydrofuran / 2 h / 20 °C

4.1: tetrahydrofuran / 6 h / 20 °C

4.2: 78 percent / NaOH; H₂O₂ / tetrahydrofuran; methanol / 24 h / 20 °C

5.1: 93 percent / NaH / dimethylformamide; tetrahydrofuran / 96 h / 20 °C

With sodium tetrahydroborate; disodium hydrogenphosphate; cerium(III) chloride; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.3390/10080901

Reference yield:

: 133218-74-3
4,5,6-tri-O-benzyl-1,2-anhydro-myo-inositol

: 214203-48-2
1-methoxy-4-[[(1S,2R,3R,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]-1-cyclohexyl]oxymethyl]benzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: 93 percent / NaH / dimethylformamide; tetrahydrofuran / 2 h / 20 °C

2.1: tetrahydrofuran / 6 h / 20 °C

2.2: 78 percent / NaOH; H₂O₂ / tetrahydrofuran; methanol / 24 h / 20 °C

3.1: 93 percent / NaH / dimethylformamide; tetrahydrofuran / 96 h / 20 °C

With sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.3390/10080901