(S)-5-((tert-butyldimethylsilyloxy)methyl)-1-(4,5-dimethoxy-2-nitrobenzoyl)-2,5-dihydro-1H-pyrrol-3-yl trifluoromethanesulfonate

Base Information

Chemical Name:(S)-5-((tert-butyldimethylsilyloxy)methyl)-1-(4,5-dimethoxy-2-nitrobenzoyl)-2,5-dihydro-1H-pyrrol-3-yl trifluoromethanesulfonate
CAS No.:637035-43-9
Molecular Formula:C₂₁H₂₉F₃N₂O₉SSi
Molecular Weight:570.616
Hs Code.:

Synonyms:(S)-5-((tert-butyldimethylsilyloxy)methyl)-1-(4,5-dimethoxy-2-nitrobenzoyl)-2,5-dihydro-1H-pyrrol-3-yl trifluoromethanesulfonate

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Chemical Property of (S)-5-((tert-butyldimethylsilyloxy)methyl)-1-(4,5-dimethoxy-2-nitrobenzoyl)-2,5-dihydro-1H-pyrrol-3-yl trifluoromethanesulfonate

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Technology Process of (S)-5-((tert-butyldimethylsilyloxy)methyl)-1-(4,5-dimethoxy-2-nitrobenzoyl)-2,5-dihydro-1H-pyrrol-3-yl trifluoromethanesulfonate

There total 6 articles about (S)-5-((tert-butyldimethylsilyloxy)methyl)-1-(4,5-dimethoxy-2-nitrobenzoyl)-2,5-dihydro-1H-pyrrol-3-yl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 2-5-chloropyridine

: 637035-41-7
(5S)-5-[[tert-butyl(dimethyl)silyl]oxymethyl]-1-(4,5-dimethoxy-2-nitro-benzoyl)pyrrolidin-3-one

: 637035-43-9
(S)-5-((tert-butyldimethylsilyloxy)methyl)-1-(4,5-dimethoxy-2-nitrobenzoyl)-2,5-dihydro-1H-pyrrol-3-yl trifluoromethanesulfonate

Guidance literature:: (5S)-5-[[tert-butyl(dimethyl)silyl]oxymethyl]-1-(4,5-dimethoxy-2-nitro-benzoyl)pyrrolidin-3-one; With sodium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 1h;

2-5-chloropyridine; In tetrahydrofuran; at -30 - 25 ℃; for 4h; Further stages.;
DOI:10.1039/b303274d

Reference yield: 50.0%

: 37595-74-7
N,N-phenylbistrifluoromethane-sulfonimide

: 637035-41-7
(5S)-5-[[tert-butyl(dimethyl)silyl]oxymethyl]-1-(4,5-dimethoxy-2-nitro-benzoyl)pyrrolidin-3-one

: 637035-43-9
(S)-5-((tert-butyldimethylsilyloxy)methyl)-1-(4,5-dimethoxy-2-nitrobenzoyl)-2,5-dihydro-1H-pyrrol-3-yl trifluoromethanesulfonate

Guidance literature:: (5S)-5-[[tert-butyl(dimethyl)silyl]oxymethyl]-1-(4,5-dimethoxy-2-nitro-benzoyl)pyrrolidin-3-one; With sodium hexamethyldisilazane; In tetrahydrofuran;

N,N-phenylbistrifluoromethane-sulfonimide; In tetrahydrofuran;
DOI:10.1021/jm901722v

Reference yield:

: 2-5-chloropyridine

: 637035-41-7
(5S)-5-[[tert-butyl(dimethyl)silyl]oxymethyl]-1-(4,5-dimethoxy-2-nitro-benzoyl)pyrrolidin-3-one

: 637035-43-9
(S)-5-((tert-butyldimethylsilyloxy)methyl)-1-(4,5-dimethoxy-2-nitrobenzoyl)-2,5-dihydro-1H-pyrrol-3-yl trifluoromethanesulfonate

: trifluoro-methanesulfonic acid 5-(tert-butyl-dimethyl-silanyloxymethyl)-1-(4,5-dimethoxy-2-nitro-benzoyl)-4,5-dihydro-1H-pyrrol-3-yl ester

Guidance literature:: (5S)-5-[[tert-butyl(dimethyl)silyl]oxymethyl]-1-(4,5-dimethoxy-2-nitro-benzoyl)pyrrolidin-3-one; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1h;

2-5-chloropyridine; In tetrahydrofuran; at -30 - 25 ℃; for 4h; Further stages.;
DOI:10.1039/b303274d