methyl 1-benzoyloxy-4-ethoxycarbonylamino-2,5-cyclohexadien-3-carboxylate

Base Information

Chemical Name:methyl 1-benzoyloxy-4-ethoxycarbonylamino-2,5-cyclohexadien-3-carboxylate
CAS No.:84525-55-3
Molecular Formula:C₁₈H₁₉NO₆
Molecular Weight:345.352
Hs Code.:

Synonyms:methyl 1-benzoyloxy-4-ethoxycarbonylamino-2,5-cyclohexadien-3-carboxylate

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Chemical Property of methyl 1-benzoyloxy-4-ethoxycarbonylamino-2,5-cyclohexadien-3-carboxylate

Chemical Property:

Purity/Quality:

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MSDS Files:: SDS file from LookChem

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Technology Process of methyl 1-benzoyloxy-4-ethoxycarbonylamino-2,5-cyclohexadien-3-carboxylate

There total 5 articles about methyl 1-benzoyloxy-4-ethoxycarbonylamino-2,5-cyclohexadien-3-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 84525-46-2
1-benzoyloxy-4-ethoxycarbonylamino-1(E),3(E)-butadiene

: 922-67-8
propynoic acid methyl ester

: 84525-55-3
methyl 1-benzoyloxy-4-ethoxycarbonylamino-2,5-cyclohexadien-3-carboxylate

Guidance literature:: With hydroquinone; In dichloromethane; at 80 ℃; for 48h; under 6000480 Torr;
DOI:10.1055/s-1982-30020

Reference yield:

: 24338-67-8
4-benzoyloxy-trans-2-trans-4-pentadienal

: 84525-55-3
methyl 1-benzoyloxy-4-ethoxycarbonylamino-2,5-cyclohexadien-3-carboxylate

Guidance literature:: Multi-step reaction with 5 steps

1: 60 percent / resorcinol, sodium chlorite / ethanol / 24 h / Ambient temperature; buffer (aq. solution citric acid and trisodium salt citric acid) - pH=3,6

2: thionyl chloride, hydroquinone / 2 h / 50 °C

3: 78 percent / azidotrimethylsilane / CH₂Cl₂ / 30 h / 0 °C

4: 63 percent / hydroquinone / toluene; dioxane / 0.33 h / Heating

5: 70 percent / hydroquinone / CH₂Cl₂ / 48 h / 80 °C / 6000480 Torr

With sodium chlorite; thionyl chloride; trimethylsilylazide; hydroquinone; recorcinol; In 1,4-dioxane; ethanol; dichloromethane; toluene;
DOI:10.1055/s-1982-30020

Reference yield:

: 84525-44-0
5-benzoyloxy-2(E),4(E)-pentadienoyl chloride

: 84525-55-3
methyl 1-benzoyloxy-4-ethoxycarbonylamino-2,5-cyclohexadien-3-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 78 percent / azidotrimethylsilane / CH₂Cl₂ / 30 h / 0 °C

2: 63 percent / hydroquinone / toluene; dioxane / 0.33 h / Heating

3: 70 percent / hydroquinone / CH₂Cl₂ / 48 h / 80 °C / 6000480 Torr

With trimethylsilylazide; hydroquinone; In 1,4-dioxane; dichloromethane; toluene;
DOI:10.1055/s-1982-30020