Bu₄NBHCl₃

Base Information

• Chemical Name: Bu₄NBHCl₃
• CAS No.: 69969-98-8
• Molecular Formula: BCl₃H*C₁₆H₃₆N
• Molecular Weight: 360.646
• Mol file: 69969-98-8.mol

Synonyms:Bu₄NBHCl₃

Chemical Property of Bu₄NBHCl₃

Chemical Property:

Purity/Quality:

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Technology Process of Bu₄NBHCl₃

There total 2 articles about Bu₄NBHCl₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

boron trichloride (10294-34-5) + tetrabutylammonium borohydride → Bu4NBHCl3 (69969-98-8) + diborane (19287-45-7)

Guidance literature:

In dichloromethane; BCl3 condensing under N2 at -196°C onto ammonium salt in CH2Cl2,warming to room temp., stirring for 2 h, cooling to -78°C, volatiles fractionating, diborane collecting at -196°C; identified by IR spectrum;

DOI:10.1021/ic00135a048

Reference yield: 65.0%

(CH3(CH2)3)4N(1+)*B3H8(1-)=(CH3(CH2)3)4NB3H8 (53451-55-1) + boron trichloride (10294-34-5) → tetraborane (18283-93-7) + Bu4NBHCl3 (69969-98-8) + diborane (19287-45-7)

Guidance literature:

In neat (no solvent); BCl3 condensing under N2 at -196°C onto ammonium salt, warming to 0°C, stirring for 1 h, cooling to -196°C, warming slowlyto room temp. while the volatiles pumping off, borane collecting at -140°C; identified by IR spectrum;

DOI:10.1021/ic00135a048

upstream raw materials:

boron trichloride

(CH₃(CH₂)3)4N⁽¹⁺⁾*B₃H₈^(1-)=(CH₃(CH₂)3)4NB₃H₈