[(1R,3S,5R)-6,6-dimethyl-2-methylenebicyclo[3.1.1]hept-3-yl]diphenylphosphine oxide

Base Information

Chemical Name:[(1R,3S,5R)-6,6-dimethyl-2-methylenebicyclo[3.1.1]hept-3-yl]diphenylphosphine oxide
CAS No.:768402-57-9
Molecular Formula:C₂₂H₂₅OP
Molecular Weight:336.414
Hs Code.:

Synonyms:[(1R,3S,5R)-6,6-dimethyl-2-methylenebicyclo[3.1.1]hept-3-yl]diphenylphosphine oxide

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Chemical Property of [(1R,3S,5R)-6,6-dimethyl-2-methylenebicyclo[3.1.1]hept-3-yl]diphenylphosphine oxide

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Technology Process of [(1R,3S,5R)-6,6-dimethyl-2-methylenebicyclo[3.1.1]hept-3-yl]diphenylphosphine oxide

There total 1 articles about [(1R,3S,5R)-6,6-dimethyl-2-methylenebicyclo[3.1.1]hept-3-yl]diphenylphosphine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 19894-97-4
(1R)-Myrtenol

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 768402-57-9
[(1R,3S,5R)-6,6-dimethyl-2-methylenebicyclo[3.1.1]hept-3-yl]diphenylphosphine oxide

Guidance literature:: With dmap; In toluene; at 100 ℃; for 48h;
DOI:10.1016/j.tetasy.2004.05.045

Reference yield: 67.0%

: 937-14-4
3-chloro-benzenecarboperoxoic acid

: 768402-57-9
[(1R,3S,5R)-6,6-dimethyl-2-methylenebicyclo[3.1.1]hept-3-yl]diphenylphosphine oxide

: 768402-58-0
[(1S,2S,3S,5R)-3-(diphenylphosphinoyl)-6,6-dimethylbicyclo[3.1.1]hept-2-yl]methanol

Guidance literature:: [(1R,3S,5R)-6,6-dimethyl-2-methylenebicyclo[3.1.1]hept-3-yl]diphenylphosphine oxide; With 9-bora-bicyclo[3.3.1]nonane; In tetrahydrofuran; at 70 ℃; for 12h;

3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; at 15 - 20 ℃; for 1h; Cooling with acetone-dry ice;

Reference yield: 67.0%

: 768402-57-9
[(1R,3S,5R)-6,6-dimethyl-2-methylenebicyclo[3.1.1]hept-3-yl]diphenylphosphine oxide

: 768402-58-0
[(1S,2S,3S,5R)-3-(diphenylphosphinoyl)-6,6-dimethylbicyclo[3.1.1]hept-2-yl]methanol

Guidance literature:: [(1R,3S,5R)-6,6-dimethyl-2-methylenebicyclo[3.1.1]hept-3-yl]diphenylphosphine oxide; With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 70 ℃; for 12h;

With 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; at 15 - 20 ℃;
DOI:10.1016/j.tetasy.2004.05.045