(2S,4S,6R)-2-phenyl-6-[(E)-styryl]tetrahydro-2H-pyran-4-yl-4-nitrobenzoate

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Chemical Name:(2S,4S,6R)-2-phenyl-6-[(E)-styryl]tetrahydro-2H-pyran-4-yl-4-nitrobenzoate
CAS No.:956035-52-2
Molecular Formula:C₂₆H₂₃NO₅
Molecular Weight:429.472
Hs Code.:

Synonyms:(2S,4S,6R)-2-phenyl-6-[(E)-styryl]tetrahydro-2H-pyran-4-yl-4-nitrobenzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,4S,6R)-2-phenyl-6-[(E)-styryl]tetrahydro-2H-pyran-4-yl-4-nitrobenzoate

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Technology Process of (2S,4S,6R)-2-phenyl-6-[(E)-styryl]tetrahydro-2H-pyran-4-yl-4-nitrobenzoate

There total 2 articles about (2S,4S,6R)-2-phenyl-6-[(E)-styryl]tetrahydro-2H-pyran-4-yl-4-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 951325-91-0
(2S,4R,6R,E)-2-phenyl-6-styryltetrahydro-2H-pyran-4-ol

: 62-23-7
4-nitro-benzoic acid

: 956035-52-2
(2S,4S,6R)-2-phenyl-6-[(E)-styryl]tetrahydro-2H-pyran-4-yl-4-nitrobenzoate

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In toluene; at 20 ℃; for 3h;
DOI:10.1055/s-2007-984886

Reference yield:

: 956035-49-7
(2S,4R,6R)-2-phenyl-6-[(E)-styryl]tetrahydro-2H-pyran-4-yl acetate

: 956035-52-2
(2S,4S,6R)-2-phenyl-6-[(E)-styryl]tetrahydro-2H-pyran-4-yl-4-nitrobenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: K₂CO₃ / methanol / 0.25 h / 20 °C

2: 90 percent / PPh₃; DIAD / toluene / 3 h / 20 °C

With di-isopropyl azodicarboxylate; potassium carbonate; triphenylphosphine; In methanol; toluene; 2: Mitsunobu reaction;
DOI:10.1055/s-2007-984886

Reference yield: 89.0%

: 956035-52-2
(2S,4S,6R)-2-phenyl-6-[(E)-styryl]tetrahydro-2H-pyran-4-yl-4-nitrobenzoate

: 956035-54-4
(2R,4S,6S)-2-(2-oxo-2-phenylethyl)-6-phenyltetrahydro-2H-pyran-4-yl-4-nitrobenzoate

Guidance literature:: With oxygen; copper(l) chloride; palladium dichloride; In water; N,N-dimethyl-formamide; at 50 - 55 ℃; for 72h;
DOI:10.1055/s-2007-984886