Methanesulfonic acid (1S,2S,3R)-2-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-cyclohexyl ester

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Chemical Name:Methanesulfonic acid (1S,2S,3R)-2-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-cyclohexyl ester
CAS No.:128434-36-6
Molecular Formula:C₁₇H₃₄O₄SSi
Molecular Weight:362.606
Hs Code.:

Synonyms:Methanesulfonic acid (1S,2S,3R)-2-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-cyclohexyl ester

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Chemical Property of Methanesulfonic acid (1S,2S,3R)-2-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-cyclohexyl ester

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Technology Process of Methanesulfonic acid (1S,2S,3R)-2-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-cyclohexyl ester

There total 3 articles about Methanesulfonic acid (1S,2S,3R)-2-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 128434-35-5
(1S,2R,3R)-2-But-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-cyclohexanol

: 124-63-0
methanesulfonyl chloride

: 128434-36-6
Methanesulfonic acid (1S,2S,3R)-2-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-cyclohexyl ester

Guidance literature:: With triethylamine; In dichloromethane; for 0.5h; 1.) -78 deg C, 2.) 0 deg C;
DOI:10.1016/S0040-4039(00)70644-7

Reference yield:

: 1192-78-5,26828-72-8,26828-73-9,72029-31-3,89064-04-0,92841-93-5,120522-60-3,126059-76-5,127379-33-3
(1R*,2R*,3S*)-2,3-epoxycyclohexanol

: 128434-36-6
Methanesulfonic acid (1S,2S,3R)-2-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-cyclohexyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 54 percent / 10percent CuI / tetrahydrofuran / 2 h / 1.) -78 deg C, 2.) room temp.

2: 1.) NaH / 1.) THF, room temp., 2.) 12 h

3: 96 percent / NEt₃ / CH₂Cl₂ / 0.5 h / 1.) -78 deg C, 2.) 0 deg C

With copper(l) iodide; sodium hydride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(00)70644-7

Reference yield:

: 128434-32-2
(1R,2R,3S)-2-But-3-enyl-cyclohexane-1,3-diol

: 128434-36-6
Methanesulfonic acid (1S,2S,3R)-2-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-cyclohexyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaH / 1.) THF, room temp., 2.) 12 h

2: 96 percent / NEt₃ / CH₂Cl₂ / 0.5 h / 1.) -78 deg C, 2.) 0 deg C

With sodium hydride; triethylamine; In dichloromethane;
DOI:10.1016/S0040-4039(00)70644-7