(3-dimethylaminopropyl)triphenylstannane

Base Information

Chemical Name:(3-dimethylaminopropyl)triphenylstannane
CAS No.:60385-55-9
Molecular Formula:C₂₃H₂₇NSn
Molecular Weight:436.184
Hs Code.:

Synonyms:(3-dimethylaminopropyl)triphenylstannane

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Chemical Property of (3-dimethylaminopropyl)triphenylstannane

Chemical Property:

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Technology Process of (3-dimethylaminopropyl)triphenylstannane

There total 3 articles about (3-dimethylaminopropyl)triphenylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 639-58-7
triphenyltin chloride

: 109-54-6
3-(Dimethylamino)propyl chloride

: 60385-55-9
(3-dimethylaminopropyl)triphenylstannane

Guidance literature:: With Mg; In tetrahydrofuran; toluene; byproducts: MgCl2; Ar-atmosphere; dropwise addn. of Grignard reagent (prepd. from Me2N(CH2)3Cl and Mg in THF) to stoich. amt. of Sn-compd. (in PhMe), standing at 21°C for 2 h; solvent removal (vac.), dissoln. in CHCl3 or CH2Cl2 (not specified), filtration, addn. to hexane (pptn.); elem. anal.;
DOI:10.1016/s0020-1693(98)00071-1

Reference yield: 70.0%

: 19070-16-7
3-(N,N-dimethylamino)propylmagnesium chloride

: 639-58-7
triphenyltin chloride

: 60385-55-9
(3-dimethylaminopropyl)triphenylstannane

Guidance literature:: In tetrahydrofuran; byproducts: MgCl2; Ar, soln. of Mg-compound added dropwise with stirring to a soln. of Sn-compound, refluxed for 1 h; most of the solvent removed, ether added, hydrolized on ice cooling (satd. NH4Cl); aq. phase extd. (ether), combined ether phase dried (Na2SO4), evapd., residue dissolved (hexane), stored overnight in a fridge,filtered, hexane removed; elem. anal.;
DOI:10.1016/0022-328X(93)80454-J

Reference yield: 44.9%

: 4167-90-2
triphenylstannyllithium

: 109-54-6
3-(Dimethylamino)propyl chloride

: 60385-55-9
(3-dimethylaminopropyl)triphenylstannane

Guidance literature:: In tetrahydrofuran; to (C6H5)3SnLi/THF (prepared in situ from Li and Ph3SnCl in THF) was slowly added the propyl chloride at -10°C, soln. stirred overnight (room temp.); addn. of 0.1M H2SO4, white ppt. extd. (water), aq. layer neutralized, extd. (15% NaOH and ether), ether layer dried (Na2SO4), evapn. (vac.), distn. (150°C, 0.1 mmHg), elem. anal.;
DOI:10.1016/0022-328X(86)84004-9