3-C-allyl-3,5-di-O-benzyl-4-C-(1(S)-(benzoyloxy)allyl)-1,2-di-O-isopropylidene-α-D-ribofuranose

Base Information

Chemical Name:3-C-allyl-3,5-di-O-benzyl-4-C-(1(S)-(benzoyloxy)allyl)-1,2-di-O-isopropylidene-α-D-ribofuranose
CAS No.:485755-39-3
Molecular Formula:C₃₅H₃₈O₇
Molecular Weight:570.683
Hs Code.:

Synonyms:3-C-allyl-3,5-di-O-benzyl-4-C-(1(S)-(benzoyloxy)allyl)-1,2-di-O-isopropylidene-α-D-ribofuranose

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Chemical Property of 3-C-allyl-3,5-di-O-benzyl-4-C-(1(S)-(benzoyloxy)allyl)-1,2-di-O-isopropylidene-α-D-ribofuranose

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Technology Process of 3-C-allyl-3,5-di-O-benzyl-4-C-(1(S)-(benzoyloxy)allyl)-1,2-di-O-isopropylidene-α-D-ribofuranose

There total 8 articles about 3-C-allyl-3,5-di-O-benzyl-4-C-(1(S)-(benzoyloxy)allyl)-1,2-di-O-isopropylidene-α-D-ribofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 98-88-4
benzoyl chloride

: 485755-38-2
3-C-allyl-3,5-di-O-benzyl-4-C-(1(S)-hydroxyallyl)-1,2-di-O-isopropylidene-α-D-ribofuranose

: 485755-39-3
3-C-allyl-3,5-di-O-benzyl-4-C-(1(S)-(benzoyloxy)allyl)-1,2-di-O-isopropylidene-α-D-ribofuranose

Guidance literature:: With pyridine;
DOI:10.1039/b205031e

Reference yield:

: 457068-00-7
3-C-allyl-3,5-di-O-benzyl-4-C-hydroxymethyl-1,2-di-O-isopropylidene-α-D-ribofuranose

: 485755-39-3
3-C-allyl-3,5-di-O-benzyl-4-C-(1(S)-(benzoyloxy)allyl)-1,2-di-O-isopropylidene-α-D-ribofuranose

Guidance literature:: Multi-step reaction with 3 steps

1: PCC / CH₂Cl₂ / 42 h / 20 °C

2: 2.95 g / tetrahydrofuran / 17 h / 20 °C

3: 98 percent / pyridine / 25 h / 20 °C

With pyridine; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.tet.2004.03.019

Reference yield:

: 197702-06-0
3-C-allyl-3-O-benzyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

: 485755-39-3
3-C-allyl-3,5-di-O-benzyl-4-C-(1(S)-(benzoyloxy)allyl)-1,2-di-O-isopropylidene-α-D-ribofuranose

Guidance literature:: Multi-step reaction with 7 steps

1: H₅IO₆ / ethyl acetate / 1.5 h / 20 °C

2: sodium hydroxide / tetrahydrofuran; H₂O / 24 h / 20 °C

3: 4.67 g / NaBH₄ / tetrahydrofuran; H₂O / 1 h / 0 °C

4: 61 percent / NaH / dimethylformamide / 1 h / 20 °C

5: PCC / CH₂Cl₂ / 42 h / 20 °C

6: 2.95 g / tetrahydrofuran / 17 h / 20 °C

7: 98 percent / pyridine / 25 h / 20 °C

With pyridine; sodium hydroxide; sodium tetrahydroborate; sodium hydride; periodic acid; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2004.03.019